nucВестник НЯЦ РКNNC RK Bulletin1729-75161729-7885Национальный ядерный центр Республики Казахстан10.52676/1729-7885-2020-1-5-11nuc-211Research ArticleСтатьиМОДИФИКАЦИЯ ПОВЕРХНОСТИ ПЭТФ ТРЕКОВЫХ МЕМБРАН ФУНКЦИОНАЛЬНЫМИ МОНОМЕРАМИ ПОД ВОЗДЕЙСТВИЕМ УСКОРЕННЫХ ЭЛЕКТРОНОВION BEAM INDUCED MODIFICATION OF THE PET ION-TRACK MEMBRANES SURFACE WITH FUNCTIONAL MONOMERSМашенцеваА. А.MashentsevaA. A.

Алматы

Астана

Almaty

Nur-Sultan

mashentseva.a@gmail.comХасенТ. Г.KhassenT. G.

Астана

Nur-Sultan

КрасновВ. А.KrasnovV. A.

Атырау

Atyrau

КасымжановМ. Т.ZhumazhanovaA. T.

Курчатов

Almaty

Nur-Sultan

ЖумажановаА. Т.KassymzhanovM. T.

Алматы

Астана

Kurchatov

Институт ядерной физики; Евразийский национальный университет им. Л.Н. ГумилеваКазахстанInstitute of Nuclear Physics; L.N. Gumilyov Eurasian National UniversityKazakhstanЕвразийский национальный университет им. Л.Н. ГумилеваКазахстанL.N. Gumilyov Eurasian National UniversityKazakhstanАтырауский университет нефти и газаКазахстанAtyrau University of Oil and GasKazakhstanАО «Парк ядерных технологий»КазахстанJSC “Park of Nuclear Technologies”Kazakhstan20203003202001511Copyright © Машенцева А.А., Хасен Т.Г., Краснов В.А., Касымжанов М.Т., Жумажанова А.Т., 20202020Машенцева А.А., Хасен Т.Г., Краснов В.А., Касымжанов М.Т., Жумажанова А.Т.Mashentseva A.A., Khassen T.G., Krasnov V.A., Zhumazhanova A.T., Kassymzhanov M.T.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journals.nnc.kz/jour/article/view/211

Данное исследование рассматривает возможность применения высокоэнергетичных электронов (3,8 МэВ, 46–200 кГр) для радиационно-прививочной модификации трековых мембран (ТМ) на основе полиэтилентерефталата (ПЭТФ) функциональным мономером акриловой кислотой (АК). Изучено влияние таких факторов как концентрация мономера, доза облучения и скорость лучевой секции конвейера ускорителя. Исходные и модифицированные образцы трековых мембран были комплексно исследованы современными-физико-химическими методами. В результате проведенных исследований были определены оптимальные условия радиационно-химического модифицирования ПЭТФ ТМ ускоренными электронами, позволяющие получать достаточно высокую степень прививки функционального мономера (акриловая кислота) с сохранением механической прочности полимерного темплата: содержание ингибитора CuSO4 – не более 1%, концентрация мономера – не более 10%, доза облучения – 100–117 кГр.

This study considers the possibility of using high-energy electrons (3.8 MeV, dose range of 46–200 kGy) for radiation-induced grafting of the polyethylene terephthalate ion-track membranes (PET ITMs) with the functional monomer of acrylic acid (AA). The effect of such factors as monomer concentration, dose, and average speed of the beam section of the accelerator conveyor was studied. The pristine and grafted samples of ion-track membranes were comprehensively studied by advanced physicochemical techniques. As a result of the studies, the optimal conditions for the radiation-induced grafting of PET ITMs with accelerated electrons were determined. A sufficiently high degree of grafting of AA while maintaining the mechanical strength of the polymer template were achieved for next conditions: the content of CuSO4 inhibitor is not more than 1%, the acrylic acid monomer concentration is not more than 10%, radiation dose in the range of 100–117 kGy.

Работа выполнена в рамках проекта АP05130797, финансируемого Министерством образования и науки Республики Казахстан.ReferencesNasef M.M., Güven O. Radiation-grafted copolymers for separation and purification purposes: Status, challenges and future directions // Prog Polym Sci – 2012. – Vol. 37. – № 12. – P. 1597–1656.Nasef M.M., Güven O. Radiation-grafted copolymers for separation and purification purposes: Status, challenges and future directions // Prog Polym Sci – 2012. – Vol. 37. – № 12. – P. 1597–1656.Huang Z., Zhang L., Cheng Z., Zhu X. Reversible Addition-Fragmentation Chain Transfer Polymerization of Acrylonitrile under Irradiation of Blue LED Light // Polymers (Basel) – 2016. – Vol. 9. – № 12. – P. 4.Huang Z., Zhang L., Cheng Z., Zhu X. Reversible Addition-Fragmentation Chain Transfer Polymerization of Acrylonitrile under Irradiation of Blue LED Light // Polymers (Basel) – 2016. – Vol. 9. – № 12. – P. 4.Chumakov M.K., Shahamat L., Weaver A., LeBlanc J., Chaychian M., Silverman J., Benjamin Richter K., et al. Electron beam induced grafting of N-isopropylacrylamide to a poly(ethylene-terephthalate) membrane for rapid cell sheet detachment // Radiat Phys Chem – 2011. – Vol. 80. – № 2. - P. 182–189.Chumakov M.K., Shahamat L., Weaver A., LeBlanc J., Chaychian M., Silverman J., Benjamin Richter K., et al. Electron beam induced grafting of N-isopropylacrylamide to a poly(ethylene-terephthalate) membrane for rapid cell sheet detachment // Radiat Phys Chem – 2011. – Vol. 80. – № 2. - P. 182–189.Zdorovets M.V., Yeszhanov A.B., Korolkov I.V., Güven O., Dosmagambetova S.S., Shlimas D.I., Zhatkanbayeva Z.K., et al. Liquid low-level radioactive wastes treatment by using hydrophobized track-etched membranes // Prog Nucl Energy – 2020. – Vol. 118. – P. 103–128.Zdorovets M.V., Yeszhanov A.B., Korolkov I.V., Güven O., Dosmagambetova S.S., Shlimas D.I., Zhatkanbayeva Z.K., et al. Liquid low-level radioactive wastes treatment by using hydrophobized track-etched membranes // Prog Nucl Energy – 2020. – Vol. 118. – P. 103–128.Liu Z., Wang W., Xie R., Ju X.-J., Chu L.-Y. Stimuli-responsive smart gating membranes // Chem Soc Rev – 2016. – Vol. 45. – P. 460–475.Liu Z., Wang W., Xie R., Ju X.-J., Chu L.-Y. Stimuli-responsive smart gating membranes // Chem Soc Rev – 2016. – Vol. 45. – P. 460–475.Chu L., Xie R., Ju X. Stimuli-responsive Membranes: Smart Tools for Controllable Mass-transfer and Separation Processes // Chinese J Chem Eng – 2011. – Vol. 19. – № 6. – P. 891–903.Chu L., Xie R., Ju X. Stimuli-responsive Membranes: Smart Tools for Controllable Mass-transfer and Separation Processes // Chinese J Chem Eng – 2011. – Vol. 19. – № 6. – P. 891–903.Wandera D., Wickramasinghe S.R., Husson S.M. Stimuli-responsive membranes // J Memb Sci – 2010. – Vol. 357. – P. 6–35.Wandera D., Wickramasinghe S.R., Husson S.M. Stimuli-responsive membranes // J Memb Sci – 2010. – Vol. 357. – P. 6–35.Chapiro A. Radiation induced grafting // Radiat Phys Chem – 1977. - Vol. 9. – P. 55–67.Chapiro A. Radiation induced grafting // Radiat Phys Chem – 1977. - Vol. 9. – P. 55–67.Nasef M.M., Gürsel S.A., Karabelli D., Güven O. Radiation-grafted materials for energy conversion and energy storage applications // Prog Polym Sci – 2016. – Vol. 63. – P. 1–41.Nasef M.M., Gürsel S.A., Karabelli D., Güven O. Radiation-grafted materials for energy conversion and energy storage applications // Prog Polym Sci – 2016. – Vol. 63. – P. 1–41.Saito K., Sugo T. High-performance polymeric materials for separation and reaction, prepared by radiation-induced graft polymerization – 2001. – P. 671–704.Saito K., Sugo T. High-performance polymeric materials for separation and reaction, prepared by radiation-induced graft polymerization – 2001. – P. 671–704.Hiroki A., Asano M., Yamaki T., Yoshida M. Effect of γ-irradiation on latent tracks of polyethylene terephthalate (PET) film // Chem Phys Lett – 2005. – Vol. 406. – P. 188–191.Hiroki A., Asano M., Yamaki T., Yoshida M. Effect of γ-irradiation on latent tracks of polyethylene terephthalate (PET) film // Chem Phys Lett – 2005. – Vol. 406. – P. 188–191.Qiu J. China’s funding system and research innovation // Natl Sci Rev – 2014. – Vol. 1. – P. 161–163.Qiu J. China’s funding system and research innovation // Natl Sci Rev – 2014. – Vol. 1. – P. 161–163.Meng T., Xie R., Chen Y.-C., Cheng C.-J., Li P.-F., Ju X.-J., Chu L.-Y. A thermo-responsive affinity membrane with nano-structured pores and grafted poly(N-isopropylacrylamide) surface layer for hydrophobic adsorption // J Memb Sci – 2010. – Vol. 349. – P. 258–267.Meng T., Xie R., Chen Y.-C., Cheng C.-J., Li P.-F., Ju X.-J., Chu L.-Y. A thermo-responsive affinity membrane with nano-structured pores and grafted poly(N-isopropylacrylamide) surface layer for hydrophobic adsorption // J Memb Sci – 2010. – Vol. 349. – P. 258–267.Toufik M., Mas A., Shkinev V., Nechaev A., Elharfi A., Schué F. Improvement of performances of PET track membranes by plasma treatment // Eur Polym J – 2002. – Vol. 38. – № 2. – P. 203–209.Toufik M., Mas A., Shkinev V., Nechaev A., Elharfi A., Schué F. Improvement of performances of PET track membranes by plasma treatment // Eur Polym J – 2002. – Vol. 38. – № 2. – P. 203–209.Soto Espinoza S.L., Arbeitman C.R., Clochard M.C., Grasselli M. Functionalization of nanochannels by radio-induced grafting polymerization on PET track-etched membranes // Radiat Phys Chem – 2014. – Vol. 94. – P. 72–75.Soto Espinoza S.L., Arbeitman C.R., Clochard M.C., Grasselli M. Functionalization of nanochannels by radio-induced grafting polymerization on PET track-etched membranes // Radiat Phys Chem – 2014. – Vol. 94. – P. 72–75.Korolkov I. V., Gorin Y.G., Yeszhanov A.B., Kozlovskiy A.L., Zdorovets M. V. Preparation of PET track-etched membranes for membrane distillation by photo-induced graft polymerization // Mater Chem Phys – 2018. – Vol. 205. – P. 55–63.Korolkov I. V., Gorin Y.G., Yeszhanov A.B., Kozlovskiy A.L., Zdorovets M. V. Preparation of PET track-etched membranes for membrane distillation by photo-induced graft polymerization // Mater Chem Phys – 2018. – Vol. 205. – P. 55–63.Wu Z., Xuewu G., Juan L., Fang W., Wenfang S., Haiyan X., Jian L. Radiation induced grafting of acrylic acid onto polycarbonate membranes // Desalination – 1987. – Vol. 62. – P. 107–115.Wu Z., Xuewu G., Juan L., Fang W., Wenfang S., Haiyan X., Jian L. Radiation induced grafting of acrylic acid onto polycarbonate membranes // Desalination – 1987. – Vol. 62. – P. 107–115.Korolkov I. V., Mashentseva A.A., Güven O., Gorin Y.G., Zdorovets M. V. Protein fouling of modified microporous PET track-etched membranes // Radiat Phys Chem – Elsevier Ltd, 2018. – Vol. 151. – № 4. – P. 141–148.Korolkov I. V., Mashentseva A.A., Güven O., Gorin Y.G., Zdorovets M. V. Protein fouling of modified microporous PET track-etched membranes // Radiat Phys Chem – Elsevier Ltd, 2018. – Vol. 151. – № 4. – P. 141–148.Sun H., Wirsén A., Albertsson A.-C. Electron Beam-Induced Graft Polymerization of Acrylic Acid and Immobilization of Arginine−Glycine−Aspartic Acid-Containing Peptide onto Nanopatterned Polycaprolactone // Biomacromolecules – 2004. – Vol. 5. – № 6. – P. 2275–2280.Sun H., Wirsén A., Albertsson A.-C. Electron Beam-Induced Graft Polymerization of Acrylic Acid and Immobilization of Arginine−Glycine−Aspartic Acid-Containing Peptide onto Nanopatterned Polycaprolactone // Biomacromolecules – 2004. – Vol. 5. – № 6. – P. 2275–2280.Grasselli M., Betz N. Electron-beam induced RAFT-graft polymerization of poly(acrylic acid) onto PVDF // Nucl Instruments Methods Phys Res Sect B Beam Interact with Mater Atoms - 2005. – Vol. 236. – P. 201–207.Grasselli M., Betz N. Electron-beam induced RAFT-graft polymerization of poly(acrylic acid) onto PVDF // Nucl Instruments Methods Phys Res Sect B Beam Interact with Mater Atoms - 2005. – Vol. 236. – P. 201–207.Kamarudin S., Mohammad M., Mohammed N. Radiation Induced Grafting of Acrylic Acid on to Polyaniline Nanofiber // Solid State Phenom - 2018. – Vol. 280. – P. 294–300.Kamarudin S., Mohammad M., Mohammed N. Radiation Induced Grafting of Acrylic Acid on to Polyaniline Nanofiber // Solid State Phenom - 2018. – Vol. 280. – P. 294–300.Korolkov I. V., Güven O., Mashentseva A.A., Atıcı A.B., Gorin Y.G., Zdorovets M. V., Taltenov A.A. Radiation induced deposition of copper nanoparticles inside the nanochannels of poly(acrylic acid)-grafted poly(ethylene terephthalate) track-etched membranes // Radiat Phys Chem – 2017. – Vol. 130. – P. 480–487.Korolkov I. V., Güven O., Mashentseva A.A., Atıcı A.B., Gorin Y.G., Zdorovets M. V., Taltenov A.A. Radiation induced deposition of copper nanoparticles inside the nanochannels of poly(acrylic acid)-grafted poly(ethylene terephthalate) track-etched membranes // Radiat Phys Chem – 2017. – Vol. 130. – P. 480–487.Mashentseva A.A. Effect of the Oxidative Modification and Activation of Templates Based on Poly (ethylene terephthalate) Track-Etched Membranes on the Electroless Deposition of Copper and the Catalytic Properties of Composite Membranes2019. – Vol. 59. – № 12. – P. 1337–1344.Mashentseva A.A. Effect of the Oxidative Modification and Activation of Templates Based on Poly (ethylene terephthalate) Track-Etched Membranes on the Electroless Deposition of Copper and the Catalytic Properties of Composite Membranes2019. – Vol. 59. – № 12. – P. 1337–1344.Korolkov I.V., Borgekov D.B., Mashentseva A.A., Güven O., Atlcl A.B., Kozlovskiy A.L., Zdorovets M.V. The effect of oxidation pretreatment of polymer template on the formation and catalytic activity of Au/PET membrane composites // Chem Pap – 2017. – Vol. 71. – P. 2353–2358.Korolkov I.V., Borgekov D.B., Mashentseva A.A., Güven O., Atlcl A.B., Kozlovskiy A.L., Zdorovets M.V. The effect of oxidation pretreatment of polymer template on the formation and catalytic activity of Au/PET membrane composites // Chem Pap – 2017. – Vol. 71. – P. 2353–2358.

The authors declare that there are no conflicts of interest present.