nucВестник НЯЦ РКNNC RK Bulletin1729-75161729-7885Национальный ядерный центр Республики Казахстан10.52676/1729-7885-2021-1-15-24nuc-311Research ArticleСтатьиИССЛЕДОВАНИЕ КИНЕТИЧЕСКИХ И ТЕРМОДИНАМИЧЕСКИХ ХАРАКТЕРИСТИК РЕАКЦИИ КАТАЛИТИЧЕСКОГО РАЗЛОЖЕНИЯ ГЕКСАЦИАНОФЕРРАТА (III) КАЛИЯ В ПРИСУТСТВИИ КОМПОЗИТНЫХ ТРЕКОВЫХ МЕМБРАНKINETIC AND THERMODYNAMIC CHARACTERISTICS OF THE POTASSIUM HEXATIONOFERRATE (III) DECOMPOSITION CATALYTIC REACTION IN THE PRESENCE OF COMPOSITE TRACK-ETCHED MEMBRANESАлтынбаеваЛ. Ш.AltynbaevaL. Sh.

Алматы, Нур-Султан

Almaty, Nur-Sultan

МендибаеваА. Ж.MendibaevaA. Zh.

Алматы, Караганда

Almaty, Karaganda

АймановаН. А.AimanovaN. A.

Алматы, Нур-Султан

Almaty, Nur-Sultan

НурмаханА. Е.NurmakhanA. E.

Алматы, Нур-ДжакуповаСултан

Almaty, Nur-Sultan

ДжакуповаЖ. Е.DzhakupovaZh. E.

Нур-Султан

Nur-Sultan

ТулеуовБ. И.TuleuovB. I.

Караганда

Karaganda

МашенцеваА. А.MashentsevaA. A.

Алматы, Нур-Султан

Almaty, Nur-Sultan

Институт ядерной физики РК; Евразийский национальный университет им. Л.Н. ГумилеваКазахстанInstitute of Nuclear Physics of the Republic of Kazakhstan; L.N. Gumilyov Eurasian National UniversityKazakhstanИнститут ядерной физики РК; Карагандинский технический университетКазахстанInstitute of Nuclear Physics of the Republic of Kazakhstan; Karaganda Technical UniversityKazakhstanЕвразийский национальный университет им. Л.Н. ГумилеваКазахстанL.N. Gumilyov Eurasian National UniversityKazakhstanКарагандинский технический университетКазахстанKaraganda Technical UniversityKazakhstan202130042021011524Copyright © Алтынбаева Л.Ш., Мендибаева А.Ж., Айманова Н.А., Нурмахан А.Е., Джакупова Ж.Е., Тулеуов Б.И., Машенцева А.А., 20212021Алтынбаева Л.Ш., Мендибаева А.Ж., Айманова Н.А., Нурмахан А.Е., Джакупова Ж.Е., Тулеуов Б.И., Машенцева А.А.Altynbaeva L.S., Mendibaeva A.Z., Aimanova N.A., Nurmakhan A.E., Dzhakupova Z.E., Tuleuov B.I., Mashentseva A.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journals.nnc.kz/jour/article/view/311

Данная работа посвящена исследованию кинетических и термодинамических характеристик процесса разложения неорганического загрязнителя сточных вод гексацианоферрата (III) калия (ГЦФК) в присутствии композитных катализаторов на основе полимерных трековых мембран (ТМ) и наночастиц (НЧ) меди. Композитные катализаторы были получены методом химического темплатного синтеза с использованием нетоксичного восстановителя - аскорбиновой кислоты. Проведено систематическое исследование процесса химического осаждения НЧ меди в зависимости от рН, времени осаждения и количества активаций полимерного темплата. Структура композитных катализаторов была исследована методами растровой электронной микроскопии и рентгеновской дифрактометрии. Каталитические свойства полученных композитов были изучены в диапазоне температур 1025 °С для серии образцов, полученных с различным временем осаждения. Показано, что кинетика реакции разложения ГЦФК соответствует реакции первого порядка. Рассчитаны такие термодинамические характеристики как энергия активации, энтропия и энтальпия активации. Изучена стабильность свойств катализаторов.

The kinetic and thermodynamic parameters of the decomposition of an inorganic wastewater pollutant such as potassium hexacyanoferrate (III) (PHCF) in the presence of composite catalysts based on polymer track membranes (TeMs) and copper nanoparticles (NPs) was studied. Composite catalysts were prepared by electroless template synthesis using a nontoxic reducing agent - ascorbic acid. A systematic study of the process of electroless plating of copper NPs was carried out depending on pH, deposition time, and the number of activations of the polymer template. The structure of the porous composite catalysts was investigated by scanning electron microscopy and X-ray diffractometry. The catalytic properties of the obtained composites were examined in the temperature range of 10-25 °C for a series of samples synthesized with different deposition times. It was shown that the kinetics of the decomposition reaction of PHCF corresponds to the pseudo first-order reaction. Such thermodynamic characteristics as energy, entropy and enthalpy of activation are calculated. The stability of the properties of catalysts has been studied.

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The authors declare that there are no conflicts of interest present.