nucВестник НЯЦ РКNNC RK Bulletin1729-75161729-7885Национальный ядерный центр Республики Казахстан10.52676/1729-7885-2022-3-45-54nuc-432Research ArticleСтатьиКРАТКИЙ ОБЗОР СИНТЕЗА, СВОЙСТВ И ПРАКТИЧЕСКОГО ПРИМЕНЕНИЯ ЛЕГИРОВАННЫХ И НЕЛЕГИРОВАННЫХ ЦИНКСОДЕРЖАЩИХ СЛОИСТЫХ ДВОЙНЫХ ГИДРОКСИДОВSYNTHESIS, PROPERTIES AND PRACTICAL APPLICATIONS OF DOPED AND UNDOPED, ZINC-CONTAINING LAYERED DOUBLE HYDROXIDES – A BRIEF REVIEWБалаеваО. О.BalayevaO. O.

Баку

Baku

oobalayeva@gmail.comБакинский государственный университетАзербайджанBaku State UniversityAzerbaijan202228092022034554Copyright © Балаева О.О., 20222022Балаева О.О.Balayeva O.O.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journals.nnc.kz/jour/article/view/432

В последнее время слоистые двойные гидроксиды (СДГ) были разработаны для применений в различных областях промышленности. В литературе рассмотрено множество методов синтеза СДГ и их классификация по изменению свойств. Однако изменение свойства методом синтеза происходит не во всех СДГ одинаково. Также при синтезе СДГ одинакового состава одним и тем же методом синтеза возможно получение СДГ с одинаковым составом, но разными свойствами за счет изменения параметров реакции. В последнее время легирование полупроводниковых нанокомпозитов атомами различных элементов привело к появлению новых свойств. Влияние элементов, используемых в процессе легирования, на свойства цинксодержащих СДГ исследовано и объяснено в обзорной статье. Методы синтеза отличаются друг от друга параметрами реакций и влияют на кристаллическую структуру, физико-химические свойства и морфологию СДГ. В обзорной статье показано обнаружение дополнительных влияний процессов легирования и природы легирующих элементов на свойства цинксодержащих СДГ, процедуры синтеза и определение параметров реакции. Редкоземельные элементы не выбираются в качестве трехвалентных металлов для основной структуры СДГ, их в основном замещают трехвалентными металлами (Al, Cr, Ti, Fe(III)) в качестве легирующих примесей из-за ионного радиуса и различных свойств.

Recently, layered double hydroxides (LDHs) have been developed for more potential applications in various industry fields. Many synthesis methods of LDHs in the literature have been considered and classified by changing properties. However, the property change by the synthesis method does not happen in the same way in all LDHs. Also, when LDH with the same composition is synthesized by the same synthesis method, it is possible to obtain LDHs with the same composition but different properties due to the change of reaction parameters. Recently, the doping of semiconductor nanocomposites with different element atoms has led to new properties. The effect of the elements used in the doping process on the properties of zinc-containing LDHs was investigated and explained in the review article. The synthesis's techniques differ from each other by the reaction parameters and they impact the crystal structure, physicochemical properties, and morphology of LDHs. Finding more additional effects of doping processes and doping elements' nature on the zinc-containing LDHs' properties, the synthesis procedures, and the determination of reaction parameters are shown in this review article. It was revealed that rare earth elements are not selected as three valence metals for the main structure of LDHs, they are mainly used as a doping element which is replaced by three valence metals (Al, Cr, Ti, Fe(III)) as dopants because of the ionic radius and various factors.

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The authors declare that there are no conflicts of interest present.