nucВестник НЯЦ РКNNC RK Bulletin1729-75161729-7885Национальный ядерный центр Республики Казахстан10.52676/1729-7885-2022-3-69-74nuc-434Research ArticleСтатьиХАРАКТЕРИЗАЦИЯ НАНОКОМПОЗИТНЫХ ЦЕОЛИТОВ ДЛЯ УДАЛЕНИЯ РТУТИ ИЗ ВОДЫ, ПОЛУЧЕННЫХ МЕТОДОМ ФЬЮЖНCHARACTERIZATION OF NANOCOMPOSITE ZEOLITES FOR MERCURY REMOVAL FROM WATER PRODUCED BY THE FUSION METHODhttps://orcid.org/0000-0003-2632-2481СатаеваА.SatayevaA.

Алматы

Нур-Султан

Almaty

Nur-Sultan

aliya.satayeva@nu.edu.kzТауановЖ.TauanovZh.

Алматы

Almaty

zhtauanov@alumni.nu.edu.kzЖантикеевУ.ZhantikeevU.

Алматы

Almaty

nurlybekov_ulan@mail.ruБайменовА.BaimenovA.

Алматы

Almaty

alzhan.baimenov@nu.edu.kzАзатС.AzatS.

Алматы

Almaty

seytkhan.azat@gmail.comАлланИ.AlanI.

Алматы

Almaty

islam.102.ima@gmail.comТОО «Жалын»; Назарбаев Университет, “National Laboratory Astana”КазахстанZhalyn LLP; Nazarbayev University, National Laboratory AstanaKazakhstanТОО «Жалын»; Казахский национальный университет им. Аль-Фараби, Факультет химии и химической технологииКазахстанZhalyn LLP; Al-Farabi Kazakh National University, Faculty of Chemistry and Chemical TechnologyKazakhstanТОО «Жалын»; Казахский национальный университет им. Аль-Фараби, Факультет химии и химической технологии; Казахский национальный исследовательский технический университет им. К.И. СатпаеваКазахстанZhalyn LLP; Al-Farabi Kazakh National University, Faculty of Chemistry and Chemical Technology; Kazakh National Research Technical University named after K.I. SatbayevKazakhstanКазахский национальный университет им. Аль-Фараби, Факультет химии и химической технологииКазахстанAl-Farabi Kazakh National University, Faculty of Chemistry and Chemical TechnologyKazakhstan202228092022036974Copyright © Сатаева А., Тауанов Ж., Жантикеев У., Байменов А., Азат С., Аллан И., 20222022Сатаева А., Тауанов Ж., Жантикеев У., Байменов А., Азат С., Аллан И.Satayeva A., Tauanov Z., Zhantikeev U., Baimenov A., Azat S., Alan I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journals.nnc.kz/jour/article/view/434

В статье приведены результаты разработки новых композитных материалов, полученных из летучей золы угля (ЛЗУ) методом Фьюжн.Композитные материалы легированы наночастицами серебра и охарактеризованы с использованием передовых методов определения их структурных показателей, а именно: рентгенофазового анализа (XRD), сканирующей электронной микроскопии с элементами полуколичественного анализа (SEM-EDS) и рентгенофлуоренцентного анализа (XRF). В ходе получения синтетических цеолитов на основе ЛЗУ структурная модификация проводилась для быстрого связывания цеолитов с ртутью при удалении ее из водной среды и улучшения качества воды. Синтезированные нанокомпозиты использовались для удаления ртути из водных растворов с различным pH. Установлено, что равновесие адсорбционной способности для синтетических цеолитов наступает примерно через 2 недели, в то время как для исходных ЛЗУ достигается в течение месяца. Предварительные результаты показывают значительно высокое удаление ртути из раствора – от 80 до 90% от исходной концентрации.

The article presents the results of the development of new composite materials obtained from coal fly ash (CFA) by the Fusion method.The composite materials are doped with silver nanoparticles and characterized using advanced characterization methods, namely XRD, SEM-EDS, XRF. In the course of obtaining synthetic zeolites based on CFA, structural modification was carried out to quickly bind zeolites with mercury when it was removed from the aqueous medium and improve the physicochemical properties. The synthesized nanocomposites were used to remove Hg from aqueous solutions with different pH. It was found that the equilibrium of the adsorption capacity for synthetic zeolites occurs after about 2 weeks, while for the original CFA it is reached within a month. Preliminary results show a significantly high removal of mercury from the solution – from 80 to 90% of mercury ions.

адсорбцияртутьцеолитысинтетические нанокомпозитылетучая золаadsorptionmercuryzeolitessynthesized nanocompositesfly ashРабота выполнена в рамках проекта МОН РК, ИРН проекта: AP08857007 «Синтетические магнитные композиты, полученные из летучей золы угля для решения водно-экологических проблем загрязнения ртутью».ReferencesSeitkhan Azat, Synthesis of biosourced silica-Ag nanocomposites and amalgamation reaction with mercury in aqueous solutions / Azat Seitkhan, Elizabeth Arkhangelsky, Thanasis Papathanasiou, Antonis A. Zorpas, Askar Abirov and Vassilis J. Inglezakis // Comptes Rendus Chimie. – 2020. – Volume 23, issue 1. – P. 77–92.Seitkhan Azat, Synthesis of biosourced silica-Ag nanocomposites and amalgamation reaction with mercury in aqueous solutions / Azat Seitkhan, Elizabeth Arkhangelsky, Thanasis Papathanasiou, Antonis A. Zorpas, Askar Abirov and Vassilis J. Inglezakis // Comptes Rendus Chimie. – 2020. – Volume 23, issue 1. – P. 77–92.Gomes, M.V.T. Phytoremediation of water contaminated with mercury using Typha domingensis in constructed wetland / M. V. T. Gomes, R. R. de Souza, V. S. Teles, E. Araújo Mendes, // Chemosphere. – 2014. – Vol. 103. – P. 228–233.Gomes, M.V.T. Phytoremediation of water contaminated with mercury using Typha domingensis in constructed wetland / M. V. T. Gomes, R. R. de Souza, V. S. Teles, E. Araújo Mendes, // Chemosphere. – 2014. – Vol. 103. – P. 228–233.Saranya, K. Bioremediation of mercury by vibrio fluvialis screened from industrial effluents / K. Saranya, A. Sundaramanickam, S. Shekhar, S. Swaminathan, T. Balasubramanian // Biomed Res. Int. – Volume 2017. – Article ID 6509648. https://doi.org/10.1155/2017/6509648Saranya, K. Bioremediation of mercury by vibrio fluvialis screened from industrial effluents / K. Saranya, A. Sundaramanickam, S. Shekhar, S. Swaminathan, T. Balasubramanian // Biomed Res. Int. – Volume 2017. – Article ID 6509648. https://doi.org/10.1155/2017/6509648Chiarle, S. Mercury removal from water by ion exchange resins adsorption / S. Chiarle, M. Ratto, M. Rovatti // Water Research. – 2000. 34(11). – P. 2971–2978.Chiarle, S. Mercury removal from water by ion exchange resins adsorption / S. Chiarle, M. Ratto, M. Rovatti // Water Research. – 2000. 34(11). – P. 2971–2978.Zhang, F.-S. Mercury removal from water using activated carbons derived from organic sewage sludge / F.-S. Zhang, J. O. Nriagu, H. Itoh // Water Res. – 2005, 39. – P. 389–395.Zhang, F.-S. Mercury removal from water using activated carbons derived from organic sewage sludge / F.-S. Zhang, J. O. Nriagu, H. Itoh // Water Res. – 2005, 39. – P. 389–395.Chojnacki, A. The application of natural zeolites for mercury removal: From laboratory tests to industrial scale / A. Chojnacki, K. Chojnacka, J. Hoffmann, H. Górecki // Miner. Eng. – 2004. 17. – P. 933–937.Chojnacki, A. The application of natural zeolites for mercury removal: From laboratory tests to industrial scale / A. Chojnacki, K. Chojnacka, J. Hoffmann, H. Górecki // Miner. Eng. – 2004. 17. – P. 933–937.Azimi, A. Removal of Heavy Metals from Industrial Wastewaters: A Review / A. Azimi, A. Azari, M. Rezakazemi, M. Ansarpour // ChemBioEng Rev. – 2017. 4 – P. 37–59Azimi, A. Removal of Heavy Metals from Industrial Wastewaters: A Review / A. Azimi, A. Azari, M. Rezakazemi, M. Ansarpour // ChemBioEng Rev. – 2017. 4 – P. 37–59Arkhangelsky, E. Nanoparticles as a Powerful Tool for Membrane Pore Size Determination and Mercury Removal / E. Arkhangelsky, V. Inglezakis, V. Gitis, A.V. Korobeinyk // Chapter in book: Nanotechnology in Water and Wastewater Treatment. – P. 63–86.Arkhangelsky, E. Nanoparticles as a Powerful Tool for Membrane Pore Size Determination and Mercury Removal / E. Arkhangelsky, V. Inglezakis, V. Gitis, A.V. Korobeinyk // Chapter in book: Nanotechnology in Water and Wastewater Treatment. – P. 63–86.Gottardi, G. Mineralogy and crystal chemistry of zeolites in: Sand / G. Gottardi, L. Mumpton, F. (eds.) // Natural Zeolites, Oxford: Pergamon. – 1978. – P. 31–442.Gottardi, G. Mineralogy and crystal chemistry of zeolites in: Sand / G. Gottardi, L. Mumpton, F. (eds.) // Natural Zeolites, Oxford: Pergamon. – 1978. – P. 31–442.Gottardi, G.; Galli, E.Natural zeolites, Berlin: SpringerVerlag, 1985. Passaglia, E.; Sheppard, R. A.: The crystal chemistry of zeolites, in:Bish, D. L.; Ming, D. W. (eds.): Natural zeolites: Occurrence, properties, applications: Reviews in mineralogy and geochemistry (45), Washington, DC: Mineralogical Society of America. – 2001 – P. 69–1164.Gottardi, G.; Galli, E.Natural zeolites, Berlin: SpringerVerlag, 1985. Passaglia, E.; Sheppard, R. A.: The crystal chemistry of zeolites, in:Bish, D. L.; Ming, D. W. (eds.): Natural zeolites: Occurrence, properties, applications: Reviews in mineralogy and geochemistry (45), Washington, DC: Mineralogical Society of America. – 2001 – P. 69–1164.Deer, W. A.; Howie, R.; Wise, W. S.; Zussmann, J.: Rock forming minerals Volume 4B: Framework silicates: Silica minerals, Feldspathoids and the Zeolites, London: Geological Society of London, 2004.Deer, W. A.; Howie, R.; Wise, W. S.; Zussmann, J.: Rock forming minerals Volume 4B: Framework silicates: Silica minerals, Feldspathoids and the Zeolites, London: Geological Society of London, 2004.Syed Salman, Conversion of coal fly ash to zeolite utilizing microwave and ultrasound energies: A review / Syed Salman Bukhar, Jamshid Behin, Hossein Kazemian, Sohrab Rohani // Fuel 140 (2015). – P. 250–266.Syed Salman, Conversion of coal fly ash to zeolite utilizing microwave and ultrasound energies: A review / Syed Salman Bukhar, Jamshid Behin, Hossein Kazemian, Sohrab Rohani // Fuel 140 (2015). – P. 250–266.Luiz Fernando Oliveira Maia, Removal of mercury (II) from contaminated water by gold-functionalised Fe3O4 magnetic nanoparticles / Luiz Fernando Oliveira Maia, Mayra Soares Santos, Thainá Gusmão Andrade, Rodrigo de Carvalho Hott, Márcia Cristina da Silva Faria, Luiz Carlos Alves Oliveira, Márcio César Pereira & Jairo Lisboa Rodrigues. // Environmental Technology. https://doi.org/10.1080/09593330.2018.1515989Luiz Fernando Oliveira Maia, Removal of mercury (II) from contaminated water by gold-functionalised Fe3O4 magnetic nanoparticles / Luiz Fernando Oliveira Maia, Mayra Soares Santos, Thainá Gusmão Andrade, Rodrigo de Carvalho Hott, Márcia Cristina da Silva Faria, Luiz Carlos Alves Oliveira, Márcio César Pereira & Jairo Lisboa Rodrigues. // Environmental Technology. https://doi.org/10.1080/09593330.2018.1515989Liu, Y. Reusable DNA-functionalized-graphene for ultrasensitive mercury (II) detection and removal. Biosens / Liu, Y., Wang, X., Wu, H. // Biosensors and Bioelectronics. – 2017. – Volume 87. – P. 129–135.Liu, Y. Reusable DNA-functionalized-graphene for ultrasensitive mercury (II) detection and removal. Biosens / Liu, Y., Wang, X., Wu, H. // Biosensors and Bioelectronics. – 2017. – Volume 87. – P. 129–135.Vassilis J. Inglezakis, Magnetic Fe3O4-Ag0 Nanocomposites for Effective Mercury Removal from Water / Vassilis J. Inglezakis, Aliya Kurbanova, Anara Molkenova, Antonis A. Zorpas and Timur Sh. Atabaev // Sustainability. – 2020, 12, 5489. https://doi.org/10.3390/su12135489.Vassilis J. Inglezakis, Magnetic Fe3O4-Ag0 Nanocomposites for Effective Mercury Removal from Water / Vassilis J. Inglezakis, Aliya Kurbanova, Anara Molkenova, Antonis A. Zorpas and Timur Sh. Atabaev // Sustainability. – 2020, 12, 5489. https://doi.org/10.3390/su12135489.Li Xian-bo, Yе Jun-jian, Liu Zhi-hong, Qiu Yue-qin, Li Long-jiang, Mao Song, Wang Xian-chen, Zhang Qin, Microwave digestion and alkali fusion assisted hydrothermal synthesis of zeolite from coal fly ash for enhanced adsorption of Cd(II) in aqueous solution. - J. Cent. South Univ. (2018) 25: 9−20, https://doi.org/10.1007/s11771-018-3712-0Li Xian-bo, Yе Jun-jian, Liu Zhi-hong, Qiu Yue-qin, Li Long-jiang, Mao Song, Wang Xian-chen, Zhang Qin, Microwave digestion and alkali fusion assisted hydrothermal synthesis of zeolite from coal fly ash for enhanced adsorption of Cd(II) in aqueous solution. - J. Cent. South Univ. (2018) 25: 9−20, https://doi.org/10.1007/s11771-018-3712-0Zhandos Tauanov, Dhawal Shah, Vassilis Inglezakis, Prashant K. Jamwal Hydrothermal synthesis of zeolite production from coal fly ash: A heuristic approach and its optimization for system identification of conversion. – Journal of Cleaner Production 182 (2018) 616 – 623.Zhandos Tauanov, Dhawal Shah, Vassilis Inglezakis, Prashant K. Jamwal Hydrothermal synthesis of zeolite production from coal fly ash: A heuristic approach and its optimization for system identification of conversion. – Journal of Cleaner Production 182 (2018) 616 – 623.Tunde V. Ojumu, Pieter W. Du Plessis, Leslie F. Petrik, Synthesis of zeolite A from coal fly ash using ultrasonic treatment – A replacement for fusion step Ultrasonics Sonochemistry 31 (2016) 342–349.Tunde V. Ojumu, Pieter W. Du Plessis, Leslie F. Petrik, Synthesis of zeolite A from coal fly ash using ultrasonic treatment – A replacement for fusion step Ultrasonics Sonochemistry 31 (2016) 342–349.

The authors declare that there are no conflicts of interest present.