nucВестник НЯЦ РКNNC RK Bulletin1729-75161729-7885Национальный ядерный центр Республики Казахстан10.52676/1729-7885-2023-1-25-39nuc-461Research ArticleСтатьиОБЗОР КОНЦЕПЦИИ ВЫСОКОЭНТРОПИЙНЫХ СПЛАВОВOVERVIEW OF THE HIGH-ENTROPY ALLOYS CONCEPThttps://orcid.org/0000-0002-0838-6724КамбаровЕ. Е.KambarovYe. Ye.

Камбаров Едыржан Ержанулы.

Усть-Каменогорск

Yedilzhan Ye. Kambarov.

Ust-Kamenogorsk

yedilzhan@gmail.comУазырхановаГ. К.UazyrkhanovaG. K.

Усть-Каменогорск

Ust-Kamenogorsk

yedilzhan@gmail.comРутковска-ГорчицаМ.Rutkowska-GorczycaM.

Вроцлав

Wroclaw

yedilzhan@gmail.comКусайновА. Е.KussainovA. Ye.

Усть-Каменогорск

Ust-Kamenogorsk

yedilzhan@gmail.comВосточно-Казахстанский технический университет им. Д. Серикбаева; Назарбаев Интеллектуальная школа химико-биологического направления г. Усть-КаменогорскКазахстанDaulet Serikbayev East Kazakhstan Technical University; Nazarbayev Intellectual School of Chemistry and Biology in Ust-KamenogorskKazakhstanВосточно-Казахстанский технический университет им. Д. СерикбаеваКазахстанDaulet Serikbayev East Kazakhstan Technical UniversityKazakhstanВроцлавский университет науки и технологийПольшаWroclaw University of Science and TechnologyPoland202330032023012539Copyright © Камбаров Е.Е., Уазырханова Г.К., Рутковска-Горчица М., Кусайнов А.Е., 20232023Камбаров Е.Е., Уазырханова Г.К., Рутковска-Горчица М., Кусайнов А.Е.Kambarov Y.Y., Uazyrkhanova G.K., Rutkowska-Gorczyca M., Kussainov A.Y.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journals.nnc.kz/jour/article/view/461

В статье представлен обзор результатов исследований высокоэнтропийных сплавов, описывающие принципы их образования, базовые понятия и свойства высокоэнтропийных сплавов. Перечислены существующие категории энтропийных сплавов. Описаны эффекты, возникающие вследствие образования высокоэнтропийных сплавов: высокая энтропия, искажение решетки, замедленная диффузия и эффект перемешивания. Отмечается, что традиционные термодинамические представления для многокомпонентных сплавов требуют дополнения. Также отмечается, что применение правил Юм-Розери для предсказывания фазового состава высокоэнтропийных сплавов показывает некоторые затруднения, так как трудно подобрать большое количество элементов, имеющих одинаковый тип решетки и валентности. Описаны результаты анализа ряда параметров и условий, которые, по мнению исследователей, влияют на структурное состояние создаваемых высокоэнтропийных сплавов, учет которых мог бы позволить корректно предсказать формирование структур в высокоэнтропийных сплавах. Анализ литературных данных показал, что в настоящее время не существует универсального параметра, который мог бы позволить корректно предсказать формирование структур в многокомпонентных системах сплавов. Представлены методы подготовки порошков высокоэнтропийных сплавов. Рассмотрены результаты работ часто используемых методов получения покрытий на основе высокоэнтропийных сплавов, таких как лазерная наплавка, магнетронное напыление, электрохимическое осаждение и термическое напыление. Описаны недостатки при получении покрытий данными методами.

The article presents a review of the results of research on high-entropy alloys, describing the principles of their formation, the basic concepts and properties of high-entropy alloys. The existing categories of the entropic alloys are listed. The effects resulting from the formation of high-entropy alloys are described: high entropy, lattice distortion, sluggish diffusion and cocktail effects. It is noted that the traditional thermodynamic representations for multicomponent alloys require additions. It is also noted that the application of Hume-Rothery rules to predict the phase composition of high-entropy alloys shows some difficulties, since it is difficult to select a large number of elements having the same type of lattice and valence. The results of the analysis of a number of parameters and conditions which, according to the researchers' opinion, affect the structural state created by high-entropy alloys, taking into account which could allow to correctly predict the formation of structures in high-entropy. Analysis of the literature data has shown that at present there is no universal parameter that could allow the correct prediction of the formation of structures in multicomponent alloys systems. Methods for the preparation of powders of high entropy alloys are presented. The results of frequently used methods of obtaining coatings on the basis of high-entropy alloys, such as laser cladding, magnetron sputtering, electrochemical deposition and thermal spraying are reviewed. Disadvantages of obtaining coatings methods are described.

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The authors declare that there are no conflicts of interest present.