nucВестник НЯЦ РКNNC RK Bulletin1729-75161729-7885Национальный ядерный центр Республики Казахстан10.52676/1729-7885-2023-3-129-136nuc-553Research ArticleСтатьиСИНТЕЗ БИОГЕННЫХ КОМПОЗИТОВ НА ОСНОВЕ ЭНДЕМИЧНОГО СЫРЬЯ РЕСПУБЛИКИ КАЗАХСТАН И ИХ ПРИМЕНЕНИЕ ДЛЯ КАТАЛИТИЧЕСКОГО УДАЛЕНИЯ ИОНОВ ХРОМАSYNTHESIS OF BIOGENIC COMPOSITES BASED ON ENDEMIC RAW MATERIALS OF THE REPUBLIC OF KAZAKHSTAN AND THEIR APPLICATION FOR CATALYTIC REMOVAL OF CHROMIUM IONSЖумабаевА. М.ZhumabayevA. M.

Алматы, Астана

Almaty, Astana

АймановаН. А.AimanovaN. A.

Алматы

Almaty

АлимхановаА. Н.AlimkhanovaA. N.

Алматы, Астана

Almaty, Astana

СейтжапарН. Г.SeitzhaparN. G.

Алматы, Астана

Almaty, Astana

КалкенА. Т.KalkenA. Т.

Астана

Astana

МашенцеваА. А.MashentsevaА. A.

Анастасия Александровна Машенцева - заведующая технологической лабораторией трековых мембран Астанинского филиала Института ядерной физики МЭ РК.

Алматы, Астана

Almaty, Astana

a.mashentseva@inp.kzНурпейсоваД. Т.NurpeisovaD. Т.

Астана

Astana

РГП «Институт ядерной физики» МЭ РК; НАО «Евразийский национальный университет им. Л.Н. Гумилева»КазахстанRSE “Institute of Nuclear Physics” ME RK; L.N. Gumilyov Eurasian National UniversityKazakhstanРГП «Институт ядерной физики» МЭ РККазахстанRSE “Institute of Nuclear Physics” ME RKKazakhstanНАО «Евразийский национальный университет им. Л.Н. Гумилева»КазахстанL.N. Gumilyov Eurasian National UniversityKazakhstan20233009202303129136Copyright © Жумабаев А.М., Айманова Н.А., Алимханова А.Н., Сейтжапар Н.Г., Калкен А.Т., Машенцева А.А., Нурпейсова Д.Т., 20232023Жумабаев А.М., Айманова Н.А., Алимханова А.Н., Сейтжапар Н.Г., Калкен А.Т., Машенцева А.А., Нурпейсова Д.Т.Zhumabayev A.M., Aimanova N.A., Alimkhanova A.N., Seitzhapar N.G., Kalken A.Т., Mashentseva А.A., Nurpeisova D.Т.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journals.nnc.kz/jour/article/view/553

Быстрое развитие нанотехнологий и интенсивное использование наноразмерных материалов в биологических и медицинских приложениях являются движущим фактором в разработке новых и улучшении существующих методов и технологий синтеза наноматериалов. Особое внимание исследователей привлекают методы зеленой химии, основанные на использовании высокоэффективных, недорогих и нетоксичных биологических ресурсов для синтеза наночастиц металлов и биогенных композитов на их основе. В отличие от традиционных методов синтеза, протоколы зеленой химии не только экологически безопасны, но также позволяют получать наноматериалы без следов примесей прекурсоров и восстановителей, используемых при синтезе. В данной работе с использованием эндемичного растительного сырья были синтезированы биогенные композиты на основе наночастиц серебра и вегетативных органов березы повислой. В качестве биогенной подложки для иммобилизации наночастиц использовали внутреннюю кору березы и березовую чагу (трутовик скошенный). Структура и состав образцов были комплексно охарактеризованы. Было изучено влияние времени допирования наночастиц на их каталитическую активность композитов в модельной реакции разложения ионов хрома (VI) под действием видимого света. Исследованы кинетические параметры реакции.

The rapid development of nanotechnology and the intensive use of nanoscale materials in biological and medical applications is the driving factor in the development of new and improvement of existing methods and technologies for the synthesis of nanomaterials. Special attention from researchers is attracted to the green chemistry methods based on the use of highly efficient, inexpensive and non-toxic biological resources for the synthesis of metal nanoparticles and their oxides. Unlike traditional methods of synthesis, green chemistry approaches are not only environmentally friendly but also make it possible to obtain nanoparticles without trace impurities used in the synthesis of precursors and reducing agents. In this work, using endemic plant materials, biogenic composites were synthesized based on silver nanoparticles and vegetative organs of silver birch (inner bark and tinder fungus (birch chaga)) used as biogenic support for the immobilization of nanoparticles. The structure and composition of the samples were comprehensively characterized. The effect of nanoparticles' loading time on the catalytic activity of resulting composites was studied in the model reaction of decomposition of chromium (VI) ions under visible light. The kinetic parameters of the reaction have been studied.

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The authors declare that there are no conflicts of interest present.