nucВестник НЯЦ РКNNC RK Bulletin1729-75161729-7885Национальный ядерный центр Республики Казахстан10.52676/1729-7885-2023-4-67-76nuc-582Research ArticleСтатьиТЕРМОЛЮМИНЕСЦЕНТНЫЕ И ДОЗИМЕТРИЧЕСКИЕ СВОЙСТВА КЕРАМИК ДИОКСИДА ЦИРКОНИЯ, ОБЛУЧЕННЫХ ВЫСОКИМИ ДОЗАМИ ИМПУЛЬСНОГО ЭЛЕКТРОННОГО ПУЧКАTHERMOLUMINESCENT AND DOSIMETRIC PROPERTIES OF ZIRCONIUM DIOXIDE CERAMICS IRRADIATED WITH HIGH DOSES OF PULSE ELECTRON BEAMНикифоровС. В.NikiforovS.ГерасимовМ. Ф.GerasimovM. F.КасаткинаЯ. П.KasatkinaYa. P.ДенисоваО. В.DenisovaO. V.ЛисицынВ. М.LisitsynV. M.ГолковскийМ. Г.GolkovskyM. G.АкилбековА. Т.AkilbekovA. T.ДаулетбековаА. М.DauletbekovaA. M.АралбаеваГ. М.AralbaevaG. M.agm_555@mail.ruАкылбековаА. Д.AkylbekobaA. D.Уральский Федеральный УниверситетКазахстанUral Federal UniversityKazakhstanТомский политехнический университетРоссияTomsk Polytechnic UniversityRussian FederationИнститут ядерной физики имени Г. И. Будкера СО РАРоссияBudker Institute of Nuclear Physics of the Siberian Branch of the RASRussian FederationЕвразийский национальный университет им. Л. Н. ГумилёваКазахстанL.N. Gumilyov Eurasian National UniversityKazakhstan202329122023046776Copyright © Никифоров С.В., Герасимов М.Ф., Касаткина Я.П., Денисова О.В., Лисицын В.М., Голковский М.Г., Акилбеков А.Т., Даулетбекова А.М., Аралбаева Г.М., Акылбекова А.Д., 20242024Никифоров С.В., Герасимов М.Ф., Касаткина Я.П., Денисова О.В., Лисицын В.М., Голковский М.Г., Акилбеков А.Т., Даулетбекова А.М., Аралбаева Г.М., Акылбекова А.Д.Nikiforov S., Gerasimov M.F., Kasatkina Y.P., Denisova O.V., Lisitsyn V.M., Golkovsky M.G., Akilbekov A.T., Dauletbekova A.M., Aralbaeva G.M., Akylbekoba A.D.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journals.nnc.kz/jour/article/view/582

В работе представлены результаты исследования термолюминесцентные (ТЛ) и дозиметрические свойства керамик моноклинного диоксида циркония двух типов: синтезированных спеканием в электрической печи при Т = 700–1700 °С и в потоке высокоэнергетических электронов (1,4 МэВ) с высокой плотностью мощности. Установлено, что отжиг керамик первого типа при Т>1000 °С приводит к существенному росту размера кристаллитов, что коррелирует со значительным увеличением интенсивности ТЛ пика при 390 К после облучения образцов высокими дозами (порядка кГр) импульсного электронного пучка (130 кэВ). Максимальным ТЛ откликом обладают керамики типа 2, синтезированные электронно-лучевым методом. В работе обсуждаются также закономерности влияния условий синтеза на кинетические параметры ТЛ и коэффициенты нелинейности дозовых зависимостей. Наличие интенсивного изолированного пика ТЛ, сублинейный характер большинства дозовых зависимостей и пренебрежимо малый фединг свидетельствуют о перспективности синтезированных в настоящей работе керамик для измерения высоких доз (единицы-десятки кГр).

The paper presents the results of a study of thermoluminescent (TL) and dosimetric properties of monoclinic zirconium dioxide ceramics of two types: synthesized by sintering in an electric furnace at T = 700–1700 °C and in a flow of high-energy electrons (1.4 MeV) with a high power density. It has been established that annealing of ceramics of the first type at T>1000 °C leads to a significant increase in the crystallite size, which correlates with a significant increase in the intensity of the TL peak at 390 K after irradiation of the samples with high doses (on the order of kGy) of a pulsed electron beam (130 keV). Type 2 ceramics synthesized by the electron beam method have the maximum TL response. The work also discusses the patterns of influence of synthesis conditions on the kinetic parameters of TL and the nonlinearity coefficients of dose dependencies. The presence of an intense isolated TL peak, the sublinear nature of most dose dependencies, and negligible fading indicate the promise of the ceramics synthesized in this work for measuring high doses (several to tens of kGy).

монокристаллыдиоксид цирконийтермолюминесциявысокоэнергетические электроныспектры поглощениябыстрые тяжелые ионыsingle crystalszirconium dioxidethermoluminescencehigh-energy electronsabsorption spectrafast heavy ionsИсследования выполнены в рамках грантового проекта AP09260057 «Люминесценция и радиационная стойкость синтезированных при различных условиях микро и наноструктурированных компактов и керамик на основе ZrO2».ReferencesC. Barry Carter, M. Grant Norton. Ceramic Materials. Science and Engineering. Springer, 2007. 716 p.C. Barry Carter, M. Grant Norton. Ceramic Materials. Science and Engineering. Springer, 2007. 716 p.Salas-Juárez, Ch.J. Afterglow based detection and dosimetry of beta particle irradiated ZrO2 / Ch.J. Salas-Juárez, C. Cruz-Vázquez, R. Avilés-Monreal, R. Bernal // Applied Radiation and Isotopes. – 2018. – Vol. 138. – P. 6–9. https://doi.org/10.1016/j.apradiso.2017.10.026Salas-Juárez, Ch.J. Afterglow based detection and dosimetry of beta particle irradiated ZrO2 / Ch.J. Salas-Juárez, C. Cruz-Vázquez, R. Avilés-Monreal, R. Bernal // Applied Radiation and Isotopes. – 2018. – Vol. 138. – P. 6–9. https://doi.org/10.1016/j.apradiso.2017.10.026Lokesha, H.S. Thermoluminescence of monoclinic ZrO2: Kinetic analysis and dosimetric features / H.S. Lokesha, M.L. Chithambo, S. Chikwembani // Journal of Luminescence. – 2020. – Vol. 218. – 116864. https://doi.org/10.1016/j.jlumin.2019.116864.Lokesha, H.S. Thermoluminescence of monoclinic ZrO2: Kinetic analysis and dosimetric features / H.S. Lokesha, M.L. Chithambo, S. Chikwembani // Journal of Luminescence. – 2020. – Vol. 218. – 116864. https://doi.org/10.1016/j.jlumin.2019.116864.Kortov, V.S. Nanophosphors and outlooks for their use in ionizing radiation detection // Radiation Measurements. – 2010. – Vol. 45. – P. 512–515. https://doi.org/10.1016/j.radmeas.2009.11.009Kortov, V.S. Nanophosphors and outlooks for their use in ionizing radiation detection // Radiation Measurements. – 2010. – Vol. 45. – P. 512–515. https://doi.org/10.1016/j.radmeas.2009.11.009Salah, N. Nanocrystalline materials for the dosimetry of heavy charged particles: A review // Radiation Physics and Chemistry. – 2011. – Vol. 80 (1). – P. 1–10. https://doi.org/10.1016/j.radphyschem.2010.08.003Salah, N. Nanocrystalline materials for the dosimetry of heavy charged particles: A review // Radiation Physics and Chemistry. – 2011. – Vol. 80 (1). – P. 1–10. https://doi.org/10.1016/j.radphyschem.2010.08.003Seid, E.T. Post-heat treatment effect on the properties of indium doped zinc oxide nanocrystals produced by the solgel method / E.T. Seid, F.B. Dejene // Optical Materials Express. – 2020. – Vol. 10. – No. 11. – P. 2849–2865. https://doi.org/10.1364/OME.400912Seid, E.T. Post-heat treatment effect on the properties of indium doped zinc oxide nanocrystals produced by the solgel method / E.T. Seid, F.B. Dejene // Optical Materials Express. – 2020. – Vol. 10. – No. 11. – P. 2849–2865. https://doi.org/10.1364/OME.400912Z. Wang, J. Zhang, G. Zheng, Y. Liu, Y. Zhao. The unusual variations of photoluminescence and afterglow properties in monoclinic ZrO2 by annealing // Journal of Luminescence. – 2012. – Vol. 132. – No. 11. – P. 2817–2821.Z. Wang, J. Zhang, G. Zheng, Y. Liu, Y. Zhao. The unusual variations of photoluminescence and afterglow properties in monoclinic ZrO2 by annealing // Journal of Luminescence. – 2012. – Vol. 132. – No. 11. – P. 2817–2821.E. Aleksanyan, M. Kirm, E. Feldbach, V. Harutyunyan. Identification of F+ centers in hafnia and zirconia nanopowders // Radiation Measurements. –2016. – Vol. 90. – P. 84–89.E. Aleksanyan, M. Kirm, E. Feldbach, V. Harutyunyan. Identification of F+ centers in hafnia and zirconia nanopowders // Radiation Measurements. –2016. – Vol. 90. – P. 84–89.Paje, S. E., and J. Llopis. Photoluminescence decay and time-resolved spectroscopy of cubic yttria-stabilized zirconia // Applied Physics A. – 1994. – Vol. 59. – No. 6. – P. 569–574.Paje, S. E., and J. Llopis. Photoluminescence decay and time-resolved spectroscopy of cubic yttria-stabilized zirconia // Applied Physics A. – 1994. – Vol. 59. – No. 6. – P. 569–574.G.M. Phatak, K Gangadharan, H Pal, JP Mittal. Luminescence properties of Ti-doped gem-grade zirconia powders // Bulletin of Materials Science. – 1994. – Vol. 17. – No. 2. – P. 163–169.G.M. Phatak, K Gangadharan, H Pal, JP Mittal. Luminescence properties of Ti-doped gem-grade zirconia powders // Bulletin of Materials Science. – 1994. – Vol. 17. – No. 2. – P. 163–169.Toshihide Ito, Motohiro Maeda, and Kazuhiko Nakamura. Similarities in photoluminescence in hafnia and zirconia induced by ultraviolet photons // Journal of applied physics. – 2005. – Vol. 97. – No. 5. – P. 054104.Toshihide Ito, Motohiro Maeda, and Kazuhiko Nakamura. Similarities in photoluminescence in hafnia and zirconia induced by ultraviolet photons // Journal of applied physics. – 2005. – Vol. 97. – No. 5. – P. 054104.Y. Cong, B. Li, S. Yue, D. Fan, X. Wang. Effect of oxygen vacancy on phase transition and photoluminescence properties of nanocrystalline zirconia synthesized by the one-pot reaction // The Journal of Physical Chemistry C. – 2009. – Vol. 113. – No. 31. – P. 13974–13978.Y. Cong, B. Li, S. Yue, D. Fan, X. Wang. Effect of oxygen vacancy on phase transition and photoluminescence properties of nanocrystalline zirconia synthesized by the one-pot reaction // The Journal of Physical Chemistry C. – 2009. – Vol. 113. – No. 31. – P. 13974–13978.Lokesha, H.S. Effect of annealing on luminescence of ZrO2 irradiated with 100 MeV Si7+ ions / H.S. Lokesha, K.R. Nagabhushana, F. Singh // Optical Materials. – 2020. – Vol. 107. – P. 109984. https://doi.org/10.1016/j.optmat.2020.109984Lokesha, H.S. Effect of annealing on luminescence of ZrO2 irradiated with 100 MeV Si7+ ions / H.S. Lokesha, K.R. Nagabhushana, F. Singh // Optical Materials. – 2020. – Vol. 107. – P. 109984. https://doi.org/10.1016/j.optmat.2020.109984Joy, K. Effects of annealing temperature on the structural and photoluminescence properties of nanocrystalline ZrO2 thin films prepared by sol-gel route / K. Joy, I.J. Berlin, P.B. Nair, J.S. Lakshmi, G.P. Daniel, P.V. Thomas // Journal of Physics and Chemistry of Solids. – 2011. – Vol. 72. – Iss. 6. – P. 673–677. https://doi.org/10.1016/j.jpcs.2011.02.012Joy, K. Effects of annealing temperature on the structural and photoluminescence properties of nanocrystalline ZrO2 thin films prepared by sol-gel route / K. Joy, I.J. Berlin, P.B. Nair, J.S. Lakshmi, G.P. Daniel, P.V. Thomas // Journal of Physics and Chemistry of Solids. – 2011. – Vol. 72. – Iss. 6. – P. 673–677. https://doi.org/10.1016/j.jpcs.2011.02.012Ashraf, S. Optical influence of annealing in nanoand submicron-scale ZrO2 powders / S. Ashraf, M. Irfan, D. Kim, J.-H.Jang, W.-T. Han, Y.-D. Jho // Ceramics International. – 2014. – Vol. 40. – Iss. 6. – P. 8513–8518. https://doi.org/10.1016/j.ceramint.2014.01.063Ashraf, S. Optical influence of annealing in nanoand submicron-scale ZrO2 powders / S. Ashraf, M. Irfan, D. Kim, J.-H.Jang, W.-T. Han, Y.-D. Jho // Ceramics International. – 2014. – Vol. 40. – Iss. 6. – P. 8513–8518. https://doi.org/10.1016/j.ceramint.2014.01.063Tamrakar, R.K. Effect of annealing temperature on thermoluminescence glow curve for UV and gamma ray induced ZrO2:Ti phosphor / R.K. Tamrakar, N. Tiwari, R.K. Kuraria, D.P. Bisen, V. Dubey, K. Upadhyay // Journal of Radiation Research and Applied Sciences. – 2015. – Vol. 8. – Iss. 1. – P. 1–10. https://doi.org/10.1016/j.jrras.2014.10.005Tamrakar, R.K. Effect of annealing temperature on thermoluminescence glow curve for UV and gamma ray induced ZrO2:Ti phosphor / R.K. Tamrakar, N. Tiwari, R.K. Kuraria, D.P. Bisen, V. Dubey, K. Upadhyay // Journal of Radiation Research and Applied Sciences. – 2015. – Vol. 8. – Iss. 1. – P. 1–10. https://doi.org/10.1016/j.jrras.2014.10.005Ghyngazov, S.A. Radiation-Thermal Sintering of Zirconia Powder Compacts Under Conditions of Bilateral Heating Using Beams of Low-Energy Electrons / S.A. Ghyngazov, T.S. Frangulyan, A.V. Chernyavskii, A.K. Goreev, E.P. Naiden // Russian Physics Journal. – 2015. – Vol. 58. – No. 2. – P. 188–191. https://doi.org/10.1007/s11182-015-0480-2Ghyngazov, S.A. Radiation-Thermal Sintering of Zirconia Powder Compacts Under Conditions of Bilateral Heating Using Beams of Low-Energy Electrons / S.A. Ghyngazov, T.S. Frangulyan, A.V. Chernyavskii, A.K. Goreev, E.P. Naiden // Russian Physics Journal. – 2015. – Vol. 58. – No. 2. – P. 188–191. https://doi.org/10.1007/s11182-015-0480-2Suvorov, S.A. Microwave Synthesis of Corundum-Zirconia Materials / S.A. Suvorov, I.A. Turkin, M.A. Dedovets // Refractories and Industrial Ceramics. – 2002. – Vol. 43. – Nos. 9–10. – P. 283–288. https://doi.org/10.1023/A:1022382431509Suvorov, S.A. Microwave Synthesis of Corundum-Zirconia Materials / S.A. Suvorov, I.A. Turkin, M.A. Dedovets // Refractories and Industrial Ceramics. – 2002. – Vol. 43. – Nos. 9–10. – P. 283–288. https://doi.org/10.1023/A:1022382431509Trindade, N.M. Synthesis and thermoluminescence properties of MgAl2O4:Ca laser-sintered ceramics / N.M. Trindade, E.P. Silva, M.C.S. Nunes, J.M. Munoz, J.C.A. Santos, E.M. Yoshimura, R.S. Silva // Optical Materials. – 2020. – Vol. 108. – P. 110181. https://doi.org/10.1016/j.optmat.2020.110181Trindade, N.M. Synthesis and thermoluminescence properties of MgAl2O4:Ca laser-sintered ceramics / N.M. Trindade, E.P. Silva, M.C.S. Nunes, J.M. Munoz, J.C.A. Santos, E.M. Yoshimura, R.S. Silva // Optical Materials. – 2020. – Vol. 108. – P. 110181. https://doi.org/10.1016/j.optmat.2020.110181Lisitsyn, V.; Mussakhanov, D.; Tulegenova, A.; Kaneva, E.; Lisitsyna, L.; Golkovski, M.; Zhunusbekov, A. The Optimization of Radiation Synthesis Modes for YAG:Ce Ceramics // Materials. – 2023. – Vol. 16. – P. 3158. https://doi.org/10.3390/ma16083158Lisitsyn, V.; Mussakhanov, D.; Tulegenova, A.; Kaneva, E.; Lisitsyna, L.; Golkovski, M.; Zhunusbekov, A. The Optimization of Radiation Synthesis Modes for YAG:Ce Ceramics // Materials. – 2023. – Vol. 16. – P. 3158. https://doi.org/10.3390/ma16083158Lisitsyn, V.; Tulegenova, A.; Kaneva, E.; Mussakhanov, D.; Gritsenko, B. Express Synthesis of YAG:Ce Ceramics in the High-Energy Electrons Flow Field // Materials. – 2023. – Vol. 16. – P. 1057. https://doi.org/10.3390/ma16031057Lisitsyn, V.; Tulegenova, A.; Kaneva, E.; Mussakhanov, D.; Gritsenko, B. Express Synthesis of YAG:Ce Ceramics in the High-Energy Electrons Flow Field // Materials. – 2023. – Vol. 16. – P. 1057. https://doi.org/10.3390/ma16031057Nikiforov, S.V. Luminescent and dosimetric properties of magnesium oxide ceramics synthesized by a high-energy electron beam / S.V. Nikiforov, V.M. Lisitsyn, D.V. Ananchenko, Y.P. Kasatkina, M.G. Golkovski, A.V. Ishchenko // Letters to the Journal of Technical Physics. – 2022. – Vol. 48. – No. 11. – P. 8–11. https://doi.org/10. 21883/PJTF.2022.11.52605.19174 (in Russian)Nikiforov, S.V. Luminescent and dosimetric properties of magnesium oxide ceramics synthesized by a high-energy electron beam / S.V. Nikiforov, V.M. Lisitsyn, D.V. Ananchenko, Y.P. Kasatkina, M.G. Golkovski, A.V. Ishchenko // Letters to the Journal of Technical Physics. – 2022. – Vol. 48. – No. 11. – P. 8–11. https://doi.org/10. 21883/PJTF.2022.11.52605.19174 (in Russian)Mehnert, R. Electron beams in research and technology // Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. – 1995. – Vol. 105 (1–4), – P. 348–358. https://doi.org/10.1016/0168-583X(95)00634-6Mehnert, R. Electron beams in research and technology // Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. – 1995. – Vol. 105 (1–4), – P. 348–358. https://doi.org/10.1016/0168-583X(95)00634-6Nasiri, S. Modified Scherrer equation to calculate crystal size by XRD with high accuracy, examples Fe2O3, TiO2 and V2O5 / S. Nasiri, M. Rabiei, A. Palevicius, G. Janusas, A. Vilkauskas, V. Nutalapati, A. Monshi // Nano Trends. – 2023. – Vol. 3. – P. 100015. https://doi.org/10.1016/j.nwnano.2023.100015Nasiri, S. Modified Scherrer equation to calculate crystal size by XRD with high accuracy, examples Fe2O3, TiO2 and V2O5 / S. Nasiri, M. Rabiei, A. Palevicius, G. Janusas, A. Vilkauskas, V. Nutalapati, A. Monshi // Nano Trends. – 2023. – Vol. 3. – P. 100015. https://doi.org/10.1016/j.nwnano.2023.100015S.V. Nikiforov, V.S. Kortov, D.L. Savushkin, A.S. Vokhmintsev, I.A. Weinstein. Thermal quenching of luminescence in nanostructured monoclinic zirconium dioxide // Radiat. Meas. – 2017. https://doi.org/10.1016/j.radmeas.2017.03.020S.V. Nikiforov, V.S. Kortov, D.L. Savushkin, A.S. Vokhmintsev, I.A. Weinstein. Thermal quenching of luminescence in nanostructured monoclinic zirconium dioxide // Radiat. Meas. – 2017. https://doi.org/10.1016/j.radmeas.2017.03.020Kiisk, V. Photo-, thermoand optically stimulated luminescence of monoclinic zirconia / V. Kiisk, L. Puust, K. Utt, A. Maaroos, H. Mändar, E. Viviani, F. Piccinelli, R. Saar, U. Joost, I. Sildos // Journal of Luminescence. – 2016. – Vol. 174. – P. 49–55. https://doi.org/10.1016/j.jlumin.2015.12.020Kiisk, V. Photo-, thermoand optically stimulated luminescence of monoclinic zirconia / V. Kiisk, L. Puust, K. Utt, A. Maaroos, H. Mändar, E. Viviani, F. Piccinelli, R. Saar, U. Joost, I. Sildos // Journal of Luminescence. – 2016. – Vol. 174. – P. 49–55. https://doi.org/10.1016/j.jlumin.2015.12.020Nikiforov, S. V., Menshenina, A. A., Konev, S. F., The influence of intrinsic and impurity defects on the luminescent properties of zirconia // J. Lumin. – 2019. – Vol. 212. – P. 219–226. https://doi.org/10.1016/j.jlumin.2019.03.062Nikiforov, S. V., Menshenina, A. A., Konev, S. F., The influence of intrinsic and impurity defects on the luminescent properties of zirconia // J. Lumin. – 2019. – Vol. 212. – P. 219–226. https://doi.org/10.1016/j.jlumin.2019.03.062Popov A.I. Basic properties of the F-type centers in halides, oxides and perovskites / A.I. Popov, E.A. Kotomin, J. Maier // Nuclear Instruments and Methods in Physics Research B. – 2010. – Vol. 268. – P. 3084–3089.Popov A.I. Basic properties of the F-type centers in halides, oxides and perovskites / A.I. Popov, E.A. Kotomin, J. Maier // Nuclear Instruments and Methods in Physics Research B. – 2010. – Vol. 268. – P. 3084–3089.Electronic excitations and defect creation in wide-gap MgO and Lu3Al5O12 crystals irradiated with swift heavy ions / A. Lushchik, T. Karner, Ch. Lushchik, K. Schwartz, F. Savikhin, E. Shablonin, A. Shugai, E. Vasil’chenko // Nuclear Instuments and Methods in Physics Research B. – 2012. – Vol. 286. – P. 200–208.Electronic excitations and defect creation in wide-gap MgO and Lu3Al5O12 crystals irradiated with swift heavy ions / A. Lushchik, T. Karner, Ch. Lushchik, K. Schwartz, F. Savikhin, E. Shablonin, A. Shugai, E. Vasil’chenko // Nuclear Instuments and Methods in Physics Research B. – 2012. – Vol. 286. – P. 200–208.Jean-Marc Costantini, François Beuneu, Didier Gourier, Christina Trautmann, Georges Calas and Marcel Toulemonde "Colour centre production in yttria-stabilized zirconia by swift charged particle irradiations // Journal of Physics: Condensed Matter. – 2004. Vol. 16. – No. 23. – P. 3957.Jean-Marc Costantini, François Beuneu, Didier Gourier, Christina Trautmann, Georges Calas and Marcel Toulemonde "Colour centre production in yttria-stabilized zirconia by swift charged particle irradiations // Journal of Physics: Condensed Matter. – 2004. Vol. 16. – No. 23. – P. 3957.Nikiforov, S.V., Kortov, V.S., Kazantseva, M.G., Petrovykh, K.A. Luminescent properties of monoclinic zirconium oxide // J. Lumin. – 2015. – Vol. 166. – P. 111–116.Nikiforov, S.V., Kortov, V.S., Kazantseva, M.G., Petrovykh, K.A. Luminescent properties of monoclinic zirconium oxide // J. Lumin. – 2015. – Vol. 166. – P. 111–116.Chen, R. and McKeever, S.W.S. Theory of Thermoluminescence and Related Phenomena // World Scientific. – 1997. – 559 p. https://doi.org/10.1142/2781Chen, R. and McKeever, S.W.S. Theory of Thermoluminescence and Related Phenomena // World Scientific. – 1997. – 559 p. https://doi.org/10.1142/2781Kitis, G., Gomez-Ros, J.M., Tuyn, J.W.N., 1998. Thermoluminescence glow-curve deconvolution functions for first, second and general orders of kinetics. J. Phys. D: Appl. Phys. – Vol. 31. – P. 2636–2641. https://doi.org/10.1088/0022-3727/31/19/037Kitis, G., Gomez-Ros, J.M., Tuyn, J.W.N., 1998. Thermoluminescence glow-curve deconvolution functions for first, second and general orders of kinetics. J. Phys. D: Appl. Phys. – Vol. 31. – P. 2636–2641. https://doi.org/10.1088/0022-3727/31/19/037Lokesha, H.S. A combined study of the thermoluminescence and electron paramagnetic resonance of point defects in ZrO2:Er3+ / H.S. Lokesha, M.L. Chithambo // Radiation Physics and Chemistry. – 2020. – Vol. 172. – P. 108767. https://doi.org/10.1016/j.radphyschem.2020.108767Lokesha, H.S. A combined study of the thermoluminescence and electron paramagnetic resonance of point defects in ZrO2:Er3+ / H.S. Lokesha, M.L. Chithambo // Radiation Physics and Chemistry. – 2020. – Vol. 172. – P. 108767. https://doi.org/10.1016/j.radphyschem.2020.108767Nikiforov, S.V. The effect of annealing temperature on the change in the structure, luminescent and dosimetric properties of ultrafine α-Al2O3 ceramics / S.V. Nikiforov, D.V. Ananchenko, G.R. Ramazanova, T.V. Shtang, A.V. Ishchenko, G.A. Yakovlev // Radiation Measurements. – 2023. – Vol. 166. – P. 106981. https://doi.org/10.1016/j.radmeas.2023.106981Nikiforov, S.V. The effect of annealing temperature on the change in the structure, luminescent and dosimetric properties of ultrafine α-Al2O3 ceramics / S.V. Nikiforov, D.V. Ananchenko, G.R. Ramazanova, T.V. Shtang, A.V. Ishchenko, G.A. Yakovlev // Radiation Measurements. – 2023. – Vol. 166. – P. 106981. https://doi.org/10.1016/j.radmeas.2023.106981Mandlik, N.T. Effect of size variation and gamma irradiation on thermoluminescence and photoluminescence characteristics of CaSO4:Eu microand nanophosphors / N.T. Mandlik, P.D. Sahare, S.D. Dhole // Applied Radiation and Isotopes. – 2020. – Vol. 159. – P. 109080. https://doi.org/10.1016/j.apradiso.2020.109080Mandlik, N.T. Effect of size variation and gamma irradiation on thermoluminescence and photoluminescence characteristics of CaSO4:Eu microand nanophosphors / N.T. Mandlik, P.D. Sahare, S.D. Dhole // Applied Radiation and Isotopes. – 2020. – Vol. 159. – P. 109080. https://doi.org/10.1016/j.apradiso.2020.109080Saran, M. Thermoluminescence in Eu doped NaLi2PO4TLD nanophosphor: Effect of particle size on TL characteristics / M. Saran, P.D. Sahare, V. Chauhan, R. Kumar, N.T. Mandlik // Journal of Luminescence. – 2021. – Vol. 238. – P. 118207. https://doi.org/10.1016/j.jlumin.2021.118207Saran, M. Thermoluminescence in Eu doped NaLi2PO4TLD nanophosphor: Effect of particle size on TL characteristics / M. Saran, P.D. Sahare, V. Chauhan, R. Kumar, N.T. Mandlik // Journal of Luminescence. – 2021. – Vol. 238. – P. 118207. https://doi.org/10.1016/j.jlumin.2021.118207Altunal, V. A calcination study on BeO ceramics for radiation dosimetry / V. Altunal, V. Guckan, A. Ozdemir, Z. Yegingil // Materials Research Bulletin. – Vol. 130. – 2020. – P. 110921. https://doi.org/10.1016/j.materresbull.2020.110921Altunal, V. A calcination study on BeO ceramics for radiation dosimetry / V. Altunal, V. Guckan, A. Ozdemir, Z. Yegingil // Materials Research Bulletin. – Vol. 130. – 2020. – P. 110921. https://doi.org/10.1016/j.materresbull.2020.110921Tsoutsoumanos, E. Nanostructured TLDs: Studying the impact of crystalline size on the Thermoluminescence glowcurve shape and electron trapping parameters / E. Tsoutsoumanos, M. Saleh, P.G. Konstantinidis, V. Altunal, P.D. Sahare, Z. Yengigil, T. Karakasidis, G. Kitis, G.S. Polymeris // Radiation Physics and Chemistry. – 2023. – Vol. 212. – P. 111067. https://doi.org/10.1016/j.radphyschem.2023.111067Tsoutsoumanos, E. Nanostructured TLDs: Studying the impact of crystalline size on the Thermoluminescence glowcurve shape and electron trapping parameters / E. Tsoutsoumanos, M. Saleh, P.G. Konstantinidis, V. Altunal, P.D. Sahare, Z. Yengigil, T. Karakasidis, G. Kitis, G.S. Polymeris // Radiation Physics and Chemistry. – 2023. – Vol. 212. – P. 111067. https://doi.org/10.1016/j.radphyschem.2023.111067J.Z. Zhang. Optical properties and spectroscopy of nanomaterials. World Scientific Publishing Co. Pte. Ltd., 2009, 400 p. https://doi.org/10.1142/7093J.Z. Zhang. Optical properties and spectroscopy of nanomaterials. World Scientific Publishing Co. Pte. Ltd., 2009, 400 p. https://doi.org/10.1142/7093Salah, N. TL and PL studies on CaSO4: Dy nanoparticles / N. Salah, P.D. Sahare, S.P. Lochab, P. Kumar // Radiation Measurements. – 2006. – Vol. 41. – Iss. 1. – P. 40–47. https://doi.org/10.1016/j.radmeas.2005.07.026Salah, N. TL and PL studies on CaSO4: Dy nanoparticles / N. Salah, P.D. Sahare, S.P. Lochab, P. Kumar // Radiation Measurements. – 2006. – Vol. 41. – Iss. 1. – P. 40–47. https://doi.org/10.1016/j.radmeas.2005.07.026Lawless, J.L., Chen, R., Pagonis, V. Sublinear dose dependence of thermoluminescence and optically stimulated luminescence prior to the approach to saturation level // Radiation Measurements. – 2009. – Vol. 44, – P. 606–610. https://doi.org/10.1016/j.radmeas.2009.03.003Lawless, J.L., Chen, R., Pagonis, V. Sublinear dose dependence of thermoluminescence and optically stimulated luminescence prior to the approach to saturation level // Radiation Measurements. – 2009. – Vol. 44, – P. 606–610. https://doi.org/10.1016/j.radmeas.2009.03.003Nikiforov, S.V., Pagonis, V., Merezhnikov, A.S. Sublinear dose dependence of thermoluminescence as a result of competition between electron and hole trapping centers // Radiation Measurements. – 2017. – Vol. 105, – P. 54–61. https://doi.org/10.1016/j.radmeas.2017.08.003Nikiforov, S.V., Pagonis, V., Merezhnikov, A.S. Sublinear dose dependence of thermoluminescence as a result of competition between electron and hole trapping centers // Radiation Measurements. – 2017. – Vol. 105, – P. 54–61. https://doi.org/10.1016/j.radmeas.2017.08.003Blair, M.W., Jacobsohn, L.G., Tornga, S.C., Ugurlu, O., Bennett, B.L., Yukihara, E.G., Muenchausen, R.E. Nanophosphor aluminum oxide: Luminescence response of a potential dosimetric material. J. Lumin. – 2010. – Vol. 130. – P. 825–831. https://doi.org/10.1016/j.jlumin.2009.12.008Blair, M.W., Jacobsohn, L.G., Tornga, S.C., Ugurlu, O., Bennett, B.L., Yukihara, E.G., Muenchausen, R.E. Nanophosphor aluminum oxide: Luminescence response of a potential dosimetric material. J. Lumin. – 2010. – Vol. 130. – P. 825–831. https://doi.org/10.1016/j.jlumin.2009.12.008

The authors declare that there are no conflicts of interest present.