nucВестник НЯЦ РКNNC RK Bulletin1729-75161729-7885Национальный ядерный центр Республики Казахстан10.52676/1729-7885-2024-2-56-64nuc-640Research ArticleСтатьиПОЛУЧЕНИЕ НАНОЦЕЛЛЮЛОЗЫ ИЗ БИОМАССЫ И ИЗУЧЕНИЕ ИХ ФИЗИКО-ХИМИЧЕСКИХ СВОЙСТВOBTAINING NANOCELLULOSE FROM BIOMASS AND STUDY OF THEIR PHYSICOCHEMICAL PROPERTIEShttps://orcid.org/0009-0002-3434-1279АбдрахмановаЛ. Е.AbdrakhmanovaL. E.

кафедра «Материаловеденеие, нанотехнологии и инженерная физика», магистрант,

Алматы

Almaty

yessenleila@bk.ruhttps://orcid.org/0000-0002-7433-1094РахимоваБ. У.RakhimovaB. U.

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Almaty

bibaarai1976@gmail.comhttps://orcid.org/0009-0003-4902-2585АлтыновЕ. А.AltynovY. A.

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Almaty

wakealtynov@gmail.comhttps://orcid.org/0000-0002-1200-2340ЖантикеевУ. Е.ZhantikeyevU. Ye.

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Almaty

nurlybekov_ulan@mail.ruhttps://orcid.org/0000-0002-5510-7660БексейтоваК. С.BexeitovaK. S.

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Almaty

bekalsu@mai.ruhttps://orcid.org/0000-0002-9705-7438АзатС.AzatS.

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Almaty

seithan@mail.ruhttps://orcid.org/0000-0002-5444-0314КудайбергеновК. К.KudaibergenovK. K.

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Almaty

k.kudaibergenov@satbayev.universityhttps://orcid.org/0000-0002-0265-4820ДаулетбайА.DauletbayA.

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Almaty

khalids@sunway.edu.myНажипкызыМ.NazhipkyzyM.

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Almaty

МoхаммaдК.MohammadK.

Селангор

Selangor

Казахский национальный исследовательский технический университет им. К. И. СатпаеваКазахстанSatbayev UniversityKazakhstanКазахский национальный университет им. Аль-ФарабиКазахстанAl-Farabi Kazakh National UniversityKazakhstanКазахский национальный исследовательский технический университет им. К. И. Сатпаева; Казахский национальный университет им. Аль-ФарабиКазахстанSatbayev University; Al-Farabi Kazakh National UniversityKazakhstanШкола инженерии и технологий, Университет СанвейМалайзияSchool of Engineering and Technology, Sunway UniversityMalaysia202430062024025664Copyright © Абдрахманова Л.Е., Рахимова Б.У., Алтынов Е.А., Жантикеев У.Е., Бексейтова К.С., Азат С., Кудайбергенов К.К., Даулетбай А., Нажипкызы М., Мoхаммaд К., 20242024Абдрахманова Л.Е., Рахимова Б.У., Алтынов Е.А., Жантикеев У.Е., Бексейтова К.С., Азат С., Кудайбергенов К.К., Даулетбай А., Нажипкызы М., Мoхаммaд К.Abdrakhmanova L.E., Rakhimova B.U., Altynov Y.A., Zhantikeyev U.Y., Bexeitova K.S., Azat S., Kudaibergenov K.K., Dauletbay A., Nazhipkyzy M., Mohammad K.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journals.nnc.kz/jour/article/view/640

В данной работе описывается получение наноцеллюлозы путем удаления лигнина из биомассы пероксидным методом в присутствии катализатора H2SO4 и изучение ее физико-химических свойств. Структура целлюлозы и модифицированной наноцеллюлозы изучалась методами Рамановской спектроскопии, ИК (инфракрасной) спектроскопии, РФА (рентгенофазный анализ), СЭМ (сканирующая электронная микроскопия). Полученное повышение кристалличности НТЦ (нановолокнистая целлюлоза) было подтверждено анализом РФА. Это указывает на то, что целлюлоза была связана с удалением аморфных частей. В результате РФА перекрытие на рентгенограммах НТЦ происходило даже в области интенсивных линий. В образце, полученном методом ИК спектроскопии, обнаружено наличие групп (3413,12 см−1; 2918,34 см−1; 1373,30 см−1; 617,52 см−1), соответствующих природе НТЦ. Сильное поглощение при 1429,8 см−1 в спектре КМЦ (карбоксилметилцеллюлозы) выявило группы -COOН, что указывает на успешное карбоксилирование целлюлозы. Изучены морфологическая поверхность, средний размер частиц и структура образцов. В результате сравнительного анализа морфологических структур выявлена характерная для волокон упорядоченная нитевидная структура нановолокнистой целлюлозы и пористая структура КМЦ с измененной поверхностью и неравномерными волокнами.

Разработанный способ получения модифицированной целлюлозы из биомассы не требует многостадийной обработки по сравнению с традиционными методами и безопасен для окружающей среды. Показано, что можно получить качественную целлюлозу в одну стадию без использования реагентов, содержащих серу и хлор, высокого давления и больших затрат воды.

This work describes the production of nanocellulose by removing lignin from biomass by the peroxide method in the presence of an H2SO4 catalyst and the study of its physicochemical properties. The structure of cellulose and modified nanocellulose was studied using Raman spectroscopy, IR (infrared) spectroscopy, X-ray diffraction, and SEM (scanning electron microscopy). The resulting increase in the crystallinity of NFC (nanofibrous cellulose) was confirmed by X-ray diffraction analysis. This indicates that cellulose was associated with the removal of amorphous parts. As a result of X-ray diffraction, overlap on NFC radiographs occurred even in the area of intense lines. In the sample obtained by IR spectroscopy, the presence of groups (3413.12 cm−1; 2918.34 cm−1; 1373.30 cm−1; 617.52 cm−1) corresponding to the nature of NFC was detected. Strong absorption at 1429.8 cm−1 in the spectrum of CMC (carboxylmethylcellulose) revealed –COOH groups, indicating successful carboxylation of cellulose. The morphological surface, average particle size and structure of the samples were studied. As a result of a comparative analysis of morphological structures, an ordered filamentous structure of nanofibrous cellulose characteristic of fibers and a porous structure of CMC with a modified surface and uneven fibers were revealed. The developed method for producing modified cellulose from biomass does not require multi-stage processing compared to traditional methods and is safe for the environment. It has been shown that it is possible to obtain high-quality cellulose in one stage without the use of reagents containing sulfur and chlorine, high pressure and high water consumption.

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The authors declare that there are no conflicts of interest present.