nucВестник НЯЦ РКNNC RK Bulletin1729-75161729-7885Национальный ядерный центр Республики Казахстан10.52676/1729-7885-2024-2-84-90nuc-648Research ArticleСтатьиСИНТЕЗ И ХАРАКТЕРИСТИКА НАНОПРОВОЛОК ZnSSYNTHESIS AND CHARACTERISTICS OF ZnS NANOWIRESАкылбековаА. Д.AkylbekovaA. D.

и.о. доцента кафедры Техническая физика, 

Астана

Astana

aiman88_88@mail.ruМухатаеваА. Ж.MukhataevaA. Zh.

магистрант кафедры Техническая физика, 

Астана

Astana

ayaulymmukhataeva@gmail.comЕвразийский национальный университет имени Л.Н. ГумилеваКазахстанEurasian National University named after L.N. GumilevKazakhstan202430062024028490Copyright © Акылбекова А.Д., Мухатаева А.Ж., 20242024Акылбекова А.Д., Мухатаева А.Ж.Akylbekova A.D., Mukhataeva A.Z.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journals.nnc.kz/jour/article/view/648

Создание нанопористого слоя диоксида кремния в структуре a-SiO2/Si-n было проведено облучением ионами ксенона на циклотроне, а затем химическое травлением водным раствором фтороводорода с добавлением палладия. Нанопоры в форме усеченных конусов имели диаметры от 486 до 509 нм. Далее нанопроволоки ZnS синтезированы методом электрохимического осаждения (ЭХО), в зависимости от напряжения на электродах электролитической ячейки и в результате получены нанопроволоки сульфида цинка с кубической структурой и пространственной группой симметрии F-43m (216).  Для образца характерны плоскости (111), (200), (220), (331) (311) соответственно, что хорошо согласуется с кубической фазой ZnS. Вольт-амперная характеристика (ВАХ) ZnS показала, что образовался полупроводник n-типа проводимости. Измерения спектров фотолюминесценции (ФЛ) ZnS регистрировали на спектрофлуориметре CM 2203. Спектры ФЛ регистрировались в диапазоне от 250 нм до 450 нм при комнатной температуре. Спектры ФЛ осажденных преципитатов обнаруживает эмиссию в широком УФ-видимом диапазоне спектров. Видно, что спектры люминесценции имеют достаточно сложные компоненты и могут быть разделены на пять гауссовых кривых. Как видно спектр ФЛ осажденного ZnS состоит из полос при 3.15 эВ, 3.3 эВ, 3.4 эВ, 3.55 эВ и 3.73 эВ. Также анализ спектров энергодисперсионный анализ показал, что нанопроволоки ZnS состоят из Zn-42,5% и S-57,5%.

The creation of a nanoporous silicon dioxide layer in the a-SiO2/Si-n structure was accomplished by irradiation with xenon ions at a cyclotron and then chemical etching with an aqueous solution of hydrogen fluoride with the addition of palladium. The truncated cone-shaped nanopores had diameters ranging from 486 to 509 nm. Then ZnS nanowires synthesized by electrochemical deposition (ECD) method, depending on the voltage at the electrodes of the electrolytic cell and as a result zinc sulfide nanowires with cubic structure and spatial symmetry group F-43m (216) were obtained. The sample is characterized by (111), (200), (220), (331) (311) planes, respectively, which is in good agreement with the cubic phase of ZnS. The charge-voltage characteristics (CVC) of ZnS showed that an n-type conductivity semiconductor was formed. Measurements of the photoluminescence (PL) spectra of ZnS were recorded on a CM 2203 spectrofluorimeter. The PL spectra were recorded in the range of 250 nm to 450 nm at room temperature. The PL spectra of the precipitated precipitates reveals emission in a wide UV-visible spectral range. It can be seen that the luminescence spectra have quite complex components and can be divided into five Gaussian curves. As can be seen the FL spectrum of the deposited ZnS consists of bands at 3.15 eV, 3.3 eV, 3.4 eV, 3.55 eV and 3.73 eV. Also analyzing the spectra energy dispersive analysis showed that the ZnS nanoproofs consist of Zn – 42.5% and S – 57.5%.

трековый темплэйт SiO2/Siэлектрохимическое осаждениенанопроволоки ZnSрентгеноструктурный анализфотолюминесценцияSiO2/Si track templateelectrochemical depositionZnS nanowiresXRD studyphotoluminescenceСтатья выполнена в рамках реализации научного проекта грантового финансирования молодых ученых по проекту «Жас Галым» на 2022–2024 годы Комитетом науки Министерства науки и высшего образования Республики Казахстан АР13268607 «Особенности формирования полупроводниковых наноструктур в трековом темплэйте SiO2/Si».ReferencesFang X., Wu L., Hu L. ZnS nanostructure arrays: a developing material star // Advanced Materials. – 2011. – Vol. 23. – No. 5. – P. 585–598.Fang X., Wu L., Hu L. ZnS nanostructure arrays: a developing material star //Advanced Materials. – 2011. – Vol. 23. – №. 5. – P. 585-598.Bol, A. A., Ferwerda, J., Bergwerff, J. A., & Meijerink, A. Luminescence of nanocrystalline ZnS: Cu2+ // Journal of Luminescence. – 2002. – Vol. 99. – No. 4. – P. 325–334.Bol, A. A., Ferwerda, J., Bergwerff, J. A., & Meijerink, A. Luminescence of nanocrystalline ZnS: Cu2+ //Journal of Luminescence. – 2002. – Vol. 99. – №. 4. – P. 325-334.Peng, H., Liuyang, B., Lingjie, Y., Jinlin, L., Fangli, Y., & Yunfa, C. Shape-controlled synthesis of ZnS nanostructures: a simple and rapid method for one-dimensional materials by plasma // Nanoscale research letters. – 2009. – Vol. 4. – P. 1047–1053.Peng, H., Liuyang, B., Lingjie, Y., Jinlin, L., Fangli, Y., & Yunfa, C. Shape-controlled synthesis of ZnS nanostructures: a simple and rapid method for one-dimensional materials by plasma //Nanoscale research letters. – 2009. – Vol. 4. – P. 1047-1053Chen H., Shi D., Qi J., Jia J., & Wang B. The stability and electronic properties of wurtzite and zinc-blende ZnS nanowires // Physics Letters A. – 2009. – Vol. 373. – No. 3. – P. 371–375.Chen H., Shi D., Qi J., Jia J., & Wang B. The stability and electronic properties of wurtzite and zinc-blende ZnS nanowires //Physics Letters A. – 2009. – Vol. 373. №. 3. – P. 371-375.Tran T.K., Park W., Tong W., Kyi M.M., Wagner B.K., & Summers C. J. Photoluminescence properties of ZnS epilayers // Journal of applied physics. – 1997. – Vol. 81. – No. 6. – P. 2803–2809.Tran T.K., Park W., Tong W., Kyi M.M., Wagner B.K., & Summers C. J.Photoluminescence properties of ZnS epilayers //Journal of applied physics. – 1997. – Vol. 81. №. 6. – P. 2803-2809.Sadovnikov S. I. Synthesis, properties and applications of semiconductor nanostructured zinc sulfide // Russian Chemical Reviews. – 2019. – Vol. 88. – No. 6. – P. 571.Sadovnikov S. I. Synthesis, properties and applications of semiconductor nanostructured zinc sulfide //Russian Chemical Reviews. – 2019. – Vol. 88. – №. 6. – P. 571.Joo J., Na H. B., Yu T., Yu J. H., Kim Y. W., Wu F., & Hyeon T. Generalized and facile synthesis of semiconducting metal sulfide nanocrystals // Journal of the American Chemical Society. – 2003. – Vol. 126. – No. 36. – P. 11100–11105.Joo J., Na H. B., Yu T., Yu J. H., Kim Y. W., Wu F., & Hyeon T. Generalized and facile synthesis of semiconducting metal sulfide nanocrystals //Journal of the American Chemical Society. – 2003. – Vol. 126. №. 36. – P. 11100-11105.Zhao Y., Zhang Y., Zhu H., Hadjipanayis G. C., & Xiao J. Q. Low-temperature synthesis of hexagonal (wurtzite) ZnS nanocrystals // Journal of the American Chemical Society. – 2004. – Vol. 126. – No. 22. – P. 6874–6875.Zhao Y., Zhang Y., Zhu H., Hadjipanayis G. C., & Xiao J. Q. Low-temperature synthesis of hexagonal (wurtzite) ZnS nanocrystals //Journal of the American Chemical Society. – 2004. – Vol. 126. №. 22. – P. 6874-6875.Li L. S., Pradhan N., Wang Y., & Peng X. High quality ZnSe and ZnS nanocrystals formed by activating zinc carboxylate precursors // Nano letters. – 2004. – Vol. 4. – No. 11. – P. 2261–2264.Li L. S., Pradhan N., Wang Y., & Peng X. High quality ZnSe and ZnS nanocrystals formed by activating zinc carboxylate precursors //Nano letters. – 2004. – Vol. 4. №. 11. – P. 2261-2264.Li L., Daou T. J., Texier I., Kim Chi T. T., Liem N. Q., & Reiss P. Highly luminescent CuInS2/ZnS core/shell nanocrystals: cadmium-free quantum dots for in vivo imaging // Chemistry of Materials. – 2009. – Vol. 21. – No. 12. – P. 2422–2429.Li L., Daou T. J., Texier I., Kim Chi T. T., Liem N. Q., & Reiss P. Highly luminescent CuInS2/ZnS core/shell nanocrystals: cadmium-free quantum dots for in vivo imaging //Chemistry of Materials. – 2009. – Vol. 21. №. 12. – P. 2422-2429.Yang Y., Chen O., Angerhofer A., & Cao Y. C.Radial‐position‐controlled doping of CdS/ZnS core/shell nanocrystals: surface effects and position‐dependent properties // Chemistry–A European Journal. – 2009. – Vol. 15. – No. 13. – P. 3186–3197.Yang Y., Chen O., Angerhofer A., & Cao Y. C.Radial‐position‐controlled doping of CdS/ZnS core/shell nanocrystals: surface effects and position‐dependent properties //Chemistry–A European Journal. – 2009. – Vol. 15. №. 13. – P. 3186-3197.Steckel J. S., Zimmer J. P., Coe‐Sullivan S., Stott N. E., Bulović V., & Bawendi M. G. Blue luminescence from (CdS) ZnS core–shell nanocrystals // Angewandte Chemie. – 2004. – Vol. 116. – No. 16. – P. 2206–2210.Steckel J. S., Zimmer J. P., Coe‐Sullivan S., Stott N. E., Bulović V., & Bawendi M. G. Blue luminescence from (CdS) ZnS core–shell nanocrystals //Angewandte Chemie. – 2004. – Vol. 116. №. 16. – P. 2206-2210.Zhou H., Fan T., Zhang D., Guo Q., & Ogawa H. Novel bacteria-templated sonochemical route for the in situ one-step synthesis of ZnS hollow nanostructures // Chemistry of Materials. – 2007. – Vol. 19. – No. 9. – P. 2144–2146.Zhou H., Fan T., Zhang D., Guo Q., & Ogawa H. Novel bacteria-templated sonochemical route for the in situ one-step synthesis of ZnS hollow nanostructures //Chemistry of Materials. – 2007. – V. 19. №. 9. – P. 2144-2146.Liu H., Ni Y., Han M., Liu Q., Xu Z., Hong J., & Ma X. A facile template-free route for synthesis of hollow hexagonal ZnS nano-and submicro-spheres // Nanotechnology. – 2005. – Vol. 16. – No. 12. – P. 2908.Liu H., Ni Y., Han M., Liu Q., Xu Z., Hong J., & Ma X. A facile template-free route for synthesis of hollow hexagonal ZnS nano-and submicro-spheres //Nanotechnology. – 2005. – Vol. 16. №. 12. – P. 2908.Shao H. F., Qian X. F., Zhu Z. K. The synthesis of ZnS hollow nanospheres with nanoporous shell // Journal of Solid State Chemistry. – 2005. – Vol. 178. No. 11. – P. 3522–3528.Shao H. F., Qian X. F., Zhu Z. K. The synthesis of ZnS hollow nanospheres with nanoporous shell //Journal of Solid State Chemistry. – 2005. – Vol. 178. №. 11. – P. 3522-3528.Bol A. A., Meijerink A. Long-lived Mn2+ emission in nanocrystalline ZnS: Mn2+ // Physical Review B. – 1998. – Vol. 58. – No. 24. – P. R15997.Bol A. A., Meijerink A. Long-lived Mn2+ emission in nanocrystalline ZnS: Mn2+ //Physical Review B. – 1998. – Vol. 58, №. 24. – С. R15997.Suyver J. F., Wuister S. F., Kelly J. J., & Meijerink A. Synthesis and photoluminescence of nanocrystalline ZnS: Mn2+ // Nano Letters. – 2001. – Vol. 1. – No. 8. – P. 429–433.Suyver J. F., Wuister S. F., Kelly J. J., & Meijerink A. Synthesis and photoluminescence of nanocrystalline ZnS: Mn2+ //Nano Letters. – 2001. – Vol. 1. № 8. – P. 429-433.Bi C., Pan L., Xu M., Yin J., Qin L., Liu J., & Xiao J. Q. Synthesis and characterization of Co-doped wurtzite ZnS nanocrystals // Materials Chemistry and Physics. – 2009. – Vol. 116. – No. 2-3. – P. 363–367.Bi C., Pan L., Xu M., Yin J., Qin L., Liu J., & Xiao J. Q., Synthesis and characterization of Co-doped wurtzite ZnS nanocrystals //Materials Chemistry and Physics. – 2009. – Vol. 116. №. 2-3. – P. 363-367.Zhong X., Liu S., Zhang Z., Li L., Wei Z., & Knoll W. Synthesis of high-quality CdS, ZnS, and Znx Cd1−xS nanocrystals using metal salts and elemental sulfur // Journal of Materials Chemistry. – 2004. – Vol. 14. –No. 18. – P. 2790–2794.Zhong X., Liu S., Zhang Z., Li L., Wei Z., & Knoll W. Synthesis of high-quality CdS, ZnS, and Zn x Cd 1− xS nanocrystals using metal salts and elemental sulfur //Journal of Materials Chemistry. – 2004. – Vol. 14. №. 18. – P. 2790-2794.Li Y. C., Ye M. F., Yang C. H., Li X. H., & Li Y. F. Composition‐and Shape‐Controlled Synthesis and Optical Properties of ZnxCd1–xS Alloyed Nanocrystals // Advanced Functional Materials. – 2005. – Vol. 15. – No. 3. – P. 433–441.Li Y. C., Ye M. F., Yang C. H., Li X. H., & Li Y. F.,Composition‐and Shape‐Controlled Synthesis and Optical Properties of ZnxCd1–xS Alloyed Nanocrystals //Advanced Functional Materials. – 2005. – Vol. 15. №. 3. – P. 433-441.Hu J., Bando Y., Liu Z., Sekiguchi T., Golberg D., & Zhan J. Epitaxial heterostructures: side-to-side Si− ZnS, Si− ZnSe biaxial nanowires, and sandwichlike ZnS− Si− ZnS triaxial nanowires // Journal of the American Chemical Society. – 2003. – Vol. 125. – No. 37. – P. 11306–11313.Hu J., Bando Y., Liu Z., Sekiguchi T., Golberg D., & Zhan J. Epitaxial heterostructures: side-to-side Si− ZnS, Si− ZnSe biaxial nanowires, and sandwichlike ZnS− Si− ZnS triaxial nanowires //Journal of the American Chemical Society. – 2003. – Vol. 125. №. 37. – P. 11306-11313.Yan J., Fang X., Zhang L., Bando Y., Gautam U. K., Dierre B., & Golberg, D. Structure and cathodoluminescence of individual ZnS/ZnO biaxial nanobelt heterostructures // Nano Letters. – 2008. – Vol. 8. – No. 9. – P. 2794–2799.Yan J., Fang X., Zhang L., Bando Y., Gautam U. K., Dierre B., & Golberg, D. Structure and cathodoluminescence of individual ZnS/ZnO biaxial nanobelt heterostructures //Nano Letters. – 2008. – Vol. 8. №. 9. – P. 2794-2799.Hu JQ, Bando Y, Zhan JH, Golberg D. Fabrication of Silica‐Shielded Ga–ZnS Metal–Semiconductor Nanowire Heterojunctions // Advanced Materials. – 2005. – Vol. 17. – No. 16. – P. 1964–1969.Hu JQ, Bando Y, Zhan JH, Golberg D. Fabrication of Silica‐Shielded Ga–ZnS Metal–Semiconductor Nanowire Heterojunctions //Advanced Materials. – 2005. – Vol. 17. №. 16. – P. 1964-1969.Lu M. Y., Song J., Lu M. P., Lee C. Y., Chen L. J., & Wang Z. L. ZnO− ZnS heterojunction and ZnS nanowire arrays for electricity generation // ACS nano. – 2009. – Vol. 3. – No. 2. – P. 357–362.Lu M. Y., Song J., Lu M. P., Lee C. Y., Chen L. J., & Wang Z. L. ZnO− ZnS heterojunction and ZnS nanowire arrays for electricity generation //ACS nano. – 2009. – Vol. 3. №. 2. – P. 357-362.Wang Y., Zhang L., Liang C., Wang G., & Peng X. Catalytic growth and photoluminescence properties of semiconductor single-crystal ZnS nanowires // Chemical Physics Letters. – 2002. – Vol. 357. – No. 3-4. – P. 314–318.Wang Y., Zhang L., Liang C., Wang G., & Peng X. Catalytic growth and photoluminescence properties of semiconductor single-crystal ZnS nanowires //Chemical Physics Letters. – 2002. – Vol. 357. №. 3-4. – P. 314-318.Biswas S., Ghoshal T., Kar S., Chakrabarti S., & Chaudhuri S. ZnS nanowire arrays: synthesis, optical and field emission properties // Crystal Growth and Design. – 2008. – Vol. 8. – No. 7. – P. 2171–2176.Biswas S., Ghoshal T., Kar S., Chakrabarti S., & Chaudhuri S. ZnS nanowire arrays: synthesis, optical and field emission properties //Crystal Growth and Design. – 2008. – Vol. 8. №. 7. – P. 2171-2176.Fang X., Bando Y., Liao M., Gautam U. K., Zhi C., Dierre B., & Golberg, D. Single‐crystalline ZnS nanobelts as ultraviolet‐light sensors // Advanced Materials. – 2009. – Vol. 21. – No. 20. – P. 2034–2039.Fang X., Bando Y., Liao M., Gautam U. K., Zhi C., Dierre B., & Golberg, D. Single‐crystalline ZnS nanobelts as ultraviolet‐light sensors //Advanced Materials. – 2009. – Vol. 21. №. 20. – P. 2034-2039.Jiang Y., Meng X. M., Liu J., Xie Z. Y., Lee C. S., & Lee S. T. Hydrogen‐assisted thermal evaporation synthesis of ZnS nanoribbons on a large scale // Advanced Materials. – 2003. – Vol. 15. – No. 4. – P. 323–327.Jiang Y., Meng X. M., Liu J., Xie Z. Y., Lee C. S., & Lee S. T. Hydrogen‐assisted thermal evaporation synthesis of ZnS nanoribbons on a large scale //Advanced Materials. – 2003. – Vol. 15. №. 4. – P. 323-327.Li J., Zhang Q., An L., Qin L., & Liu, J. Large-scale growth of millimeter-long single-crystalline ZnS nanobelts // Journal of Solid State Chemistry. – 2008. – Vol. 181. – No. 11. – P. 3116–3120.Li J., Zhang Q., An L., Qin L., & Liu, J. Large-scale growth of millimeter-long single-crystalline ZnS nanobelts //Journal of Solid State Chemistry. – 2008. – Vol. 181. №. 11. – P. 3116-3120.Fang X. S., Bando Y., Shen, G. Z., Ye C. H., Gautam U. K., Costa P. M., & Golberg D. Ultrafine ZnS nanobelts as field emitters // Advanced Materials. – 2007. – Vol. 19. – No. 18. – P. 2593–2596.Fang X. S., Bando Y., Shen, G. Z., Ye C. H., Gautam U. K., Costa P. M., & Golberg D. Ultrafine ZnS nanobelts as field emitters //Advanced Materials. – 2007. – Vol. 19. №. 18. – P. 2593-2596.Soltani N., Saion E., Hussein M. Z., Erfani M., Abedini A., Bahmanrokh G., ... & Vaziri P. Visible light-induced degradation of methylene blue in the presence of photocatalytic ZnS and CdS nanoparticles // International journal of molecular sciences. – 2012. – Vol. 13. – No. 10. – P. 12242–12258.Soltani N., Saion E., Hussein M. Z., Erfani M., Abedini A., Bahmanrokh G., ... & Vaziri P. Visible light-induced degradation of methylene blue in the presence of photocatalytic ZnS and CdS nanoparticles //International journal of molecular sciences. – 2012. – Vol. 13. №. 10. – P. 12242-12258.Kurbatov D. I., Opanasyuk N. M., Opanasyuk A. S., & Kosyak V. V. Electrophysical and Structural Properties of n-ZnS/P-CdTe Heterojunctions // Journal of Nano-and Electronic Physics. – 2009. – Vol. – No. 3. – P. 25.Kurbatov D. I., Opanasyuk N. M., Opanasyuk A. S., & Kosyak V. V. Electrophysical and Structural Properties of n-ZnS/P-CdTe Heterojunctions //Journal of Nano-and Electronic Physics. – 2009. – . Vol. – №. 3. – P. 25.Becker and Allen J. Bard. Photoluminescence and Photoinduced Oxygen Adsorption of Colloidal Zinc Sulfide Dispersions Wllllam. // J. Phys. Chem. – 1983. –Vol. 87. – P. 4889.Becker and Allen J. Bard. Photoluminescence and Photoinduced Oxygen Adsorption of Colloidal Zinc Sulfide Dispersions Wllllam. // J. Phys. Chem. – 1983. –Vol. 87. – P. 4889.Santana Y.V.B. Raubach C. W., Ferrer M. M., La Porta F., Sambrano J. R., Longo V. M., & Longo E. Experimental and theoretical studies on the enhanced photoluminescence activity of zinc sulfide with a capping agent // Journal of Applied Physics. – 2011. –Vol. 110. – P. 123507.Santana Y.V.B. Raubach C. W., Ferrer M. M., La Porta F., Sambrano J. R., Longo V. M., & Longo E. Experimental and theoretical studies on the enhanced photoluminescence activity of zinc sulfide with a capping agent // Journal of Applied Physics. – 2011. –Vol. 110. – P. 123507.Sarkar R., Tiwary C. S., Kumbhakar P., Basu S., & Mitra A. K. Yellow-orange light emission from Mn2+ doped ZnS nanoparticles // Physica E: Low-dimensional Systems and Nanostructures. – 2008. – Vol. 40. – No. 10. – P. 3115–3120.Sarkar R., Tiwary C. S., Kumbhakar P., Basu S., & Mitra A. K. Yellow-orange light emission from Mn2+ doped ZnS nanoparticles //Physica E: Low-dimensional Systems and Nanostructures. – 2008. – Vol. 40. – №. 10. – P. 3115-3120.Limaye M. V., Gokhale S., Acharya S. A., & Kulkarni S. K. Template-free ZnS nanorod synthesis by microwave irradiation // Nanotechnology. – 2008. – Vol. 19. – No. 41. – P. 415602.Limaye M. V., Gokhale S., Acharya S. A., & Kulkarni S. K. Template-free ZnS nanorod synthesis by microwave irradiation //Nanotechnology. – 2008. – Vol. 19. – №. 41. – P. 415602.Tran T. K., Park W., Tong, W., Kyi M. M., Wagner B. K., & Summers C. J. Photoluminescence properties of ZnS epilayers // Journal of Applied Physics. – 1997. – Vol. 81. – No. 6. – P. 2803–2809.Tran T. K., Park W., Tong, W., Kyi M. M., Wagner B. K., & Summers C. J. Photoluminescence properties of ZnS epilayers //Journal of Applied Physics. – 1997. – Vol. 81. – №. 6. – P. 2803-2809.

The authors declare that there are no conflicts of interest present.