nucВестник НЯЦ РКNNC RK Bulletin1729-75161729-7885Национальный ядерный центр Республики Казахстан10.52676/1729-7885-2024-3-29-34nuc-677Research ArticleСтатьиПОЛУЧЕНИЕ ЦЕЛЛЮЛОЗЫ С КРИСТАЛЛОГРАФИЧЕСКОЙ ОРИЕНТАЦИЕЙ МАКРОМОЛЕКУЛ ИЗ ЛУЗГИ ГИБРИДНОГО СОРТА ПОДСОЛНЕЧНИКАOBTAINING CELLULOSE WITH CRYSTALLOGRAPHIC ORIENTATION OF MACROMOLECULES FROM THE HUSK OF A HYBRID SUNFLOWERhttps://orcid.org/0000-0001-9779-2013ИмашеваА. А.ImashevaA. A.

Усть-Каменогорск

Алматы

Ust-Kamenogorsk

Almaty

imasheva.aidana@list.ruhttps://orcid.org/0000-0001-5760-2967КабдрахмановаС. К.KabdrakhmanovaS. K.

Алматы

Almaty

Sanaly33@mail.ruhttps://orcid.org/0000-0002-3172-623XАкатанК.AkatanK.

Усть-Каменогорск

 Ust-Kamenogorsk

Ahnur.hj@mail.ruhttps://orcid.org/0000-0003-1484-9737ИбраеваЖ. Е.IbraevaZh. E.

Алматы

Almaty

Zhanar-ibraeva@mail.ruТемирхановаГ.TemirkhanovaG.

Алматы

Almaty

https://orcid.org/0000-0001-6386-4605БейсебековМ. М.BeisebekovM. M.

Алматы

Almaty

Make1987@mail.ruhttps://orcid.org/0000-0002-5557-0081КантайН.KantayN.

Усть-Каменогорск

Алматы

Ust-Kamenogorsk

Almaty

Nurgan85@mail.ruhttps://orcid.org/0000-0002-0394-2824МаусымбаеваА. М.MausumbaevaA. M.

Талдыкурган

Taldykorgan

Aida_28.65@mail.ruВосточно-Казахстанский университет им. С. Аманжолова; Научный центр композитных материаловКазахстанS. Amanzholov East Kazakhstan University; Scientific Center of Composite MaterialsKazakhstanКазахский национальный исследовательский технический университет им. К.И. СатбаеваКазахстанSatbayev UniversityKazakhstanВосточно-Казахстанский университет им. С. АманжоловаКазахстанS. Amanzholov East Kazakhstan UniversityKazakhstanНаучный центр композитных материалов; Казахский национальный педагогический университеті им. АбаяКазахстанScientific Center of Composite Materials; Abai Kazakh National Pedagogical UniversityKazakhstanНаучный центр композитных материаловКазахстанScientific Center of Composite MaterialsKazakhstanЖетысуский университет им. И. ЖансугуроваКазахстанZhetysu University named after I. ZhansugurovKazakhstan202409102024032934Copyright © Имашева А.А., Кабдрахманова С.К., Акатан К., Ибраева Ж.Е., Темирханова Г., Бейсебеков М.М., Кантай Н., Маусымбаева А.М., 20242024Имашева А.А., Кабдрахманова С.К., Акатан К., Ибраева Ж.Е., Темирханова Г., Бейсебеков М.М., Кантай Н., Маусымбаева А.М.Imasheva A.A., Kabdrakhmanova S.K., Akatan K., Ibraeva Z.E., Temirkhanova G., Beisebekov M.M., Kantay N., Mausumbaeva A.M.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journals.nnc.kz/jour/article/view/677

В настоящее время получение и внедрение к применению  биоразлагающихся композиционных материалов на основе целлюлозы, не наносящих вреда природе, позволяют решить ряд экологических проблем. В связи с этим увеличивается количество сырья, из которого можно получить целлюлозу, широко изучаются экономическая и экологическая эффективность его использования и свойства получаемой целлюлозы.

В работе изучен процесс получения микрокристаллической целлюлозы из лузги семян подсолнечника P63LE10 «Pioneer» (США) с использованием пероксиуксусных кислот на основе ледяной уксусной кислоты и   42%-ной уксусной кислоты с уменьшенной в два раза концентрацией. В результате исследования установлено, что выход МКЦ (МКЦ2), полученных в присутствии пероксиуксусной кислоты при вдвое меньшей концентрации уксусной кислоты выше на 3,7%, а содержание α-целлюлозы выше на 3,6%. Однако количество остаточного лигнина в нем равно 24,02%, следы аморфной структуры (следовые количества аморфных структур) определены методами ИК-спектроскопии и рентгенодифрактограммы. Напротив, хотя выход и содержание α-целлюлозы МКЦ1, полученного с использованием пероксиуксусной кислоты на основе ледяной уксусной кислоты, ниже, чем у МКЦ2, но полученный продукт характеризуется высокой степенью чистоты и высоким содержанием упорядоченных частей целлюлозы с кристаллографическая ориентация макромолекул.

Currently, the obtaining and implementation of self-degradable, harmless to the nature of composite materials based on cellulose, allows to solve a number of environmental problems. In this regard, the number of raw materials sources from which cellulose can be obtained increases, the economic and environmental efficiency of its usage and the properties of the obtained cellulose can be studied. In this study, from sunflower husk (SFH)P63LE10 «Pioneer» (USA) using glacial acetic acid and based on acetic acid with 42% concentration peroxyacetic acid, process of obtaining microcrystalline cellulose comparatively was studied. As a result of the study, based on acetic acid with 42% concentration in combination peroxyacetic acid was determined, that yield of obtained MCC (MCC2) was 3,7%, and also quantity of α-cellulose was higher to 3,6%. However, the quality of the residual lignin was 24.02%, and the trace quantity of amorphous structure was determined by IR spectroscopy and XRD diffractometry. On the contrary, the yield and quantity of α-cellulose obtained MMC1 using glacial acetic acid in combination peroxyacetic acid is lower than MMC2, obtained product was different by high degree of purity and content of the ordered part of cellulose with crystallographic orientation of macromolecules.

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The authors declare that there are no conflicts of interest present.