nucВестник НЯЦ РКNNC RK Bulletin1729-75161729-7885Национальный ядерный центр Республики Казахстан10.52676/1729-7885-2025-2-132-141nuc-828Research ArticleСтатьиРАЗРАБОТКА ФУНКЦИОНАЛЬНЫХ МАТЕРИАЛОВ НА ОСНОВЕ MIL-101(Cr) МЕТАЛЛ-ОРГАНИЧЕСКИХ КАРКАСОВ: МИНИОБЗОРDEVELOPMENT OF FUNCTIONAL MATERIALS BASED ON MIL-101(Cr) METAL-ORGANIC FRAMEWORKS: A MINI REVIEWАлимхановаА. Н.AlimkhanovaA. N.

Алматы

Астана

Almaty

Astana

РакишеваС. Р.RakishevaS. R.

Алматы

Астана

Almaty

Astana

МашенцеваА. А.MashentsevaA. A.

Алматы

Астана

Almaty

Astana

mashentseva.a@gmail.comАбуоваФ. У.AbuovaF. U.

Астана

Astana

НурпейсоваД. Т.NurpeisovaD. T.

Алматы

Астана

Almaty

Astana

РГП «Институт ядерной физики» МЭ РК; Евразийский национальный университет им. Л.Н. ГумилеваКазахстанRSE “Institute of Nuclear Physics” ME RK; L.N. Gumilyov Eurasian National UniversityKazakhstanЕвразийский национальный университет им. Л.Н. ГумилеваКазахстанL.N. Gumilyov Eurasian National UniversityKazakhstan20251407202502132141Copyright © Алимханова А.Н., Ракишева С.Р., Машенцева А.А., Абуова Ф.У., Нурпейсова Д.Т., 20252025Алимханова А.Н., Ракишева С.Р., Машенцева А.А., Абуова Ф.У., Нурпейсова Д.Т.Alimkhanova A.N., Rakisheva S.R., Mashentseva A.A., Abuova F.U., Nurpeisova D.T.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journals.nnc.kz/jour/article/view/828

MIL-101(Cr) — один из наиболее хорошо изученных металлоорганических каркасов (МОК) на основе хрома, состоящий из иона металлического хрома и лиганда терефталевой кислоты. Уникальные физико-химические свойства данного МОК (сверхвысокая удельная площадь поверхности, размер пор, термическая, химическая стабильность и т.д.)  обеспечивают ему широкий спектр применения в различных областях современного материаловедения. Благодаря содержанию в структуре ненасыщенных кислотных центров Льюиса, MIL-101(Cr) может быть легко модифицирован, причем в большинстве случаев, производные демонстрируют улучшенные характеристики по сравнению с исходным МОК. В обзоре приводятся сведения об основных напрвления практического применения MIL-101(Cr) в адсорбции различных классов соединений из водных растворов, хранении и разделении газов, а также в катализе.

MIL-101(Cr) is one of the most well-studied chromium-based metal-organic frameworks (MOF) consisting of a metallic chromium ion and a terephthalic acid ligand. The unique physicochemical properties of this MOF (ultra-high specific surface area, pore size, thermal and chemical stability, etc.) provide it with a wide range of applications in various fields of advanced materials science. Due to unsaturated Lewis acid sites in the structure, MIL-101(Cr) can be easily modified. In most cases, its derivatives demonstrate significantly improved characteristics compared to the pristine MOF. The review provides information on the practical application of MIL-101(Cr) in the adsorption of various compounds from aqueous solutions, gas storage and separation, and catalysis.

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The authors declare that there are no conflicts of interest present.