nucВестник НЯЦ РКNNC RK Bulletin1729-75161729-7885Национальный ядерный центр Республики Казахстан10.52676/1729-7885-2025-3-136-146nuc-858Research ArticleСтатьиОЦЕНКА ПРИМЕНИМОСТИ ИОННОЙ МОДИФИКАЦИИ ДЛЯ ПОВЫШЕНИЯ СОПРОТИВЛЯЕМОСТИ К ВНЕШНИМ ВОЗДЕЙСТВИЯМ МНОГОСЛОЙНЫХ ПОКРЫТИЙEVALUATION OF THE APPLICABILITY OF IONIC MODIFICATION TO ENHANCE THE RESISTANCE TO EXTERNAL INFLUENCES OF MULTILAYER COATINGSКозловскийА. Л.KozlovskiyA. L.

Козловский Артем Леонидович.

Астана; Алматы

Astana; Almaty

kozlovskiy.a@inp.kzШлимасД. И.ShlimasD. I.

Астана; Алматы

Astana; Almaty

КалиекперовМ. Е.KaliekperovM. E.

Астана; Алматы

Astana; Almaty

МунасбаеваК. К.MunasbayevaK. K.

Алматы

Almaty

БоргековД. Б.BorgekovD. B.

Астана; Алматы

Astana; Almaty

НАО Евразийский национальный университет им. Л.Н. Гумилева; РГП «Институт ядерной физики» МЭ РККазахстанNJSC L.N. Gumilyov Eurasian National University; RSE “Institute of Nuclear Physics” ME RKKazakhstanРГП «Институт ядерной физики» МЭ РККазахстанRSE “Institute of Nuclear Physics” ME RKKazakhstan20252210202503136146Copyright © Козловский А.Л., Шлимас Д.И., Калиекперов М.Е., Мунасбаева К.К., Боргеков Д.Б., 20252025Козловский А.Л., Шлимас Д.И., Калиекперов М.Е., Мунасбаева К.К., Боргеков Д.Б.Kozlovskiy A.L., Shlimas D.I., Kaliekperov M.E., Munasbayeva K.K., Borgekov D.B.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journals.nnc.kz/jour/article/view/858

Ключевая цель представленных результатов исследования заключается в определении влияния ионной модификации на повышение сопротивляемости многослойных покрытий к внешним воздействиям, включая высокотемпературное окисление, воздействие агрессивных сред и механических нагрузок. В качестве метода ионной модификации был выбран метод облучения низкоэнергетическими ионами N+, C+, O+ с энергиями 40 кэВ и флюенсами 1013, 1014 и 1015 см−2, выбор которых основан на схожести их массы, а также возможности ускорения их с одинаковой энергией, что позволяет исключить энергетический фактор при оценке эффективности модификации. В ходе проведенных исследований было установлено, что эффект упрочнения, наблюдаемый при облучении низкоэнергетическими ионами имеет прямую зависимость от флюенса облучения, вариация которого приводит к формированию большей плотности структурных дефектов в поврежденном слое, а также практически не зависит от типа ионов используемых для модификации. При этом установлено, что максимальный эффект упрочнения достигается при флюенсах облучения 1015 см−2, при которых упрочнение приповерхностного слоя составляет порядка 10–15% по сравнению с немодифицированными покрытиями. Результаты оценки эффективности устойчивости к внешним механическим воздействиям, в частности, к трению, показали, что формирование деформационного слоя за счет ионной модификации приводит к увеличению сопротивляемости к износу при трении, а также увеличению стабильности поверхности покрытий к процессам деградации.

The key aim of the presented research results is to determine the effect of ionic modification on enhancement of the resistance of multilayer coatings to external influences, including high-temperature oxidation, exposure to aggressive environments and mechanical loads. The method of irradiation with low-energy N+, C+, O+ ions with energies of 40 keV and fluences of 1013, 1014 and 1015 cm−2 was chosen as the ion modification method. The choice of these ions is based on the similarity of their masses, alongside the possibility of their acceleration with the same energy, which makes it possible to exclude the energy factor during the modification efficiency assessment. During the studies conducted it was established that the strengthening effect observed during irradiation with low-energy ions has a direct dependence on the irradiation fluence, the variation of which leads to the formation of a higher density of structural defects in the damaged layer, and is also practically independent of the type of ions used for modification. Moreover, it has been established that the maximum hardening effect is achieved at irradiation fluences of 1015 cm−2, at which the hardening of the near-surface layer is about 10–15% compared to unmodified coatings. The results of the assessment of the efficiency of resistance to external mechanical influences, in particular, to friction, showed that the formation of a deformation layer due to ionic modification leads to an increase in resistance to wear during friction, as well as an increase in the stability of the coating surface to degradation processes. Tests of thermal barrier properties of coatings have shown that the use of the ion modification method leads to an increase in the thermal insulation properties of coatings by inhibiting heat transfer processes in the coatings.

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The authors declare that there are no conflicts of interest present.