КРАТКИЙ ОБЗОР СИНТЕЗА, СВОЙСТВ И ПРАКТИЧЕСКОГО ПРИМЕНЕНИЯ ЛЕГИРОВАННЫХ И НЕЛЕГИРОВАННЫХ ЦИНКСОДЕРЖАЩИХ СЛОИСТЫХ ДВОЙНЫХ ГИДРОКСИДОВ

В последнее время слоистые двойные гидроксиды (СДГ) были разработаны для применений в различных областях промышленности. В литературе рассмотрено множество методов синтеза СДГ и их классификация по изменению свойств. Однако изменение свойства методом синтеза происходит не во всех СДГ одинаково. Также при синтезе СДГ одинакового состава одним и тем же методом синтеза возможно получение СДГ с одинаковым составом, но разными свойствами за счет изменения параметров реакции. В последнее время легирование полупроводниковых нанокомпозитов атомами различных элементов привело к появлению новых свойств. Влияние элементов, используемых в процессе легирования, на свойства цинксодержащих СДГ исследовано и объяснено в обзорной статье. Методы синтеза отличаются друг от друга параметрами реакций и влияют на кристаллическую структуру, физико-химические свойства и морфологию СДГ. В обзорной статье показано обнаружение дополнительных влияний процессов легирования и природы легирующих элементов на свойства цинксодержащих СДГ, процедуры синтеза и определение параметров реакции. Редкоземельные элементы не выбираются в качестве трехвалентных металлов для основной структуры СДГ, их в основном замещают трехвалентными металлами (Al, Cr, Ti, Fe(III)) в качестве легирующих примесей из-за ионного радиуса и различных свойств.

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