OBTAINING CELLULOSE WITH CRYSTALLOGRAPHIC ORIENTATION OF MACROMOLECULES FROM THE HUSK OF A HYBRID SUNFLOWER

Currently, the obtaining and implementation of self-degradable, harmless to the nature of composite materials based on cellulose, allows to solve a number of environmental problems. In this regard, the number of raw materials sources from which cellulose can be obtained increases, the economic and environmental efficiency of its usage and the properties of the obtained cellulose can be studied. 
In this study, from sunflower husk (SFH)P63LE10 «Pioneer» (USA) using glacial acetic acid and based on acetic acid with 42% concentration peroxyacetic acid, process of obtaining microcrystalline cellulose comparatively was studied. As a result of the study, based on acetic acid with 42% concentration in combination peroxyacetic acid was determined, that yield of obtained MCC (MCC2) was 3,7%, and also quantity of α-cellulose was higher to 3,6%. However, the quality of the residual lignin was 24.02%, and the trace quantity of amorphous structure was determined by IR spectroscopy and XRD diffractometry. On the contrary, the yield and quantity of α-cellulose obtained MMC1 using glacial acetic acid in combination peroxyacetic acid is lower than MMC2, obtained product was different by high degree of purity and content of the ordered part of cellulose with crystallographic orientation of macromolecules.

1. https://www.agbz.ru/articles/utilizatsiya-otkhodovselskogo-khozyaystva

2. Zaitseva L. A., Volkova V. V., Minevich I. E. Preparation of a cellulose product from hemp husks // Polzunov Bulletin. – 2023. – No. 2. – P. 174‒183. (In Russ.)

3. K. Akatan, S. Kabdrakhmanova, T. Kuanyshbekov, Z. Ibraeva, A. Battalova, K.S. Joshy, Sabu Thomas. Highlyefficient isolation of microcrystalline cellulose and nanocellulose from sunflower seed waste via environmentally benign method // Cellulose 29(7). – May 2022. https://doi.org/10.1007/s10570-022-04527-4

4. https://bossagro.kz/26389-vko-zanimaet-1-mesto-poproizvodstvu-semyan-podsolnechnika

5. Kurniawan Tjhang Winny, Sulistyarti Hermin, Rumhayati Barlah, Sabarudin Akhmad. Cellulose Nanocrystals (CNCs) and Cellulose Nanofibers (CNFs) as Adsorbents of Heavy Metal Ions // Journal of Chemistry. – 2023. – ID5037027. – 36 pages. https://doi.org/10.1155/2023/5037027

6. Teng, C.P.; Tan, M.Y.; Toh, J.P.W.; Lim, Q.F.; Wang, X.; Ponsford, D.; Lin, E.M.J.; Thitsartarn, W.; Tee, S.Y. Advances in Cellulose-Based Composites for Energy Applications // Materials. – 2023. – Vol. 16. – P. 3856. https://doi.org/10.3390/ma16103856

7. Ye, D., Rongpipi, S., Kiemle, S.N. et al. Preferred crystallographic orientation of cellulose in plant primary cell walls // Nat Commun. – 2020. – Vol. 11. – P. 4720. https://doi.org/10.1155/2023/5037027

8. A.K. Battalova, S.K. Kabdrakhmanova, K. Akatan, M.M. Beisebekov, N. Kantay, Zh.E. Ibraeva, A.M. Mausumbayeva, L.B. Merck. Features of microcrystalline cellulose produced from sunflower seeds of different oil content // International Journal of Biology and Chemistry. – 2023. – Vol. 16. – No. 1. https://doi.org/10.26577/ijbch.2023.v16.i1.08

9. Hamid M. Shaikh; Arfat Anis; Anesh Manjaly Poulose; Saeed M. Al-Zahrani; Niyaz Ahamad Madhar; Abdullah Alhamidi; Mohammad Asif Alam. Isolation and Characterization of Alpha and Nanocrystalline Cellulose from Date Palm (Phoenix dactylifera L.) // Trunk Mesh. Polymers. – 2021. https://doi.org/10.3390/polym13111893

10. A.A. Imasheva, S.K. Kabdrakhmanova, Zh.E. Ibraeva, S.E. Kudaibergenov, K. Akatan, M.B. Abilev. Investigation of the possibility of obtaining cellulose from oily crop residues by the organosolvent method // Bulletin NNC RК. – Issue 1, March, 2020. – P. 35–39. (in Kazakh)

11. Pen R. Z., Shapiro I. L., Karetnikova N. V. Peroxide cellulose from wheat straw // Chemistry of plant raw materials, – 2022. – No. 2. – P. 299–305. URL: http://journal.asu.ru/cw/article/view/10688. (In Russ.)

12. S.B. Khusid, A.N.Gneush, E.V. Nesterenko Sunflower husks as a source of functional feed additives // Scientific Journal of KubGAU. – 2015. – No. 107 (03). (In Russ.)

13. https://gcomsort.kz

14. A.V. Vurasko, A.R. Minakova, B.N. Driker, V.P. Sivakov, A.M. Kosacheva. Technology for producing cellulose from non-wood plant raw materials // Chemistry of plant raw materials. – 2010. – No. 2. – P. 165–168. (In Russ.)

15. A.V. Vurasko, E.I. Simonova, A.R. Minakova, V.P. Sivakov. Improving the technology for producing cellulose by the oxidative-organosolvent method from non-wood plant raw materials // Chemistry of plant raw materials. – 2019. – No. 3. – P. 269–276. (In Russ.)

16. Hyeong Rae Lee, Romas J Kazlauskas, Tai Hyun Park. One-step pretreatment of yellow poplar biomass using peracetic acid to enhance enzymatic digestibility // Scientific Reports /7:12216. https://doi.org/10.1038/s41598-017-12542-w

17. O.T. Shipina., Z.T. Valishina., A.V. Kostochko. X-ray diffraction analysis of various types of cellulose // Bulletin of the Technological University. – 2015. – Vol. 18. – No. 7. (In Russ.)

18. O.K. Nugmanov, N.P. Grigorieva, N.A. Lebedev. Structural analysis of herbal cellulose // Chemistry of plant raw materials. – 2013. – No. 1. – P. 29–37. (In Russ.)