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SPECTRAL-KINETIC CHARACTERISTICS OF CATHODOLUMINESCENCE OF LANTHANIDE NIOBATES (Y,Lu,Gd)NbO4:Bi3+

https://doi.org/10.52676/1729-7885-2024-4-147-152

Abstract

The study is devoted to the study of lanthanide niobates doped with bismuth ions, which are of interest as potential phosphors used in various fields of human activity, such as medicine, industry, and science. In this paper, an experimental study of the cathodoluminescence of niobates (Y,Lu,Gd)NbO4:Bi3+, namely, spectral characteristics with time resolution, as well as the kinetics of luminescence attenuation for the main spectral bands, is carried out. The temperature dependence of the cathodoluminescence attenuation time for the YNbO4 sample is presented.:Bi3+ measured in the temperature range of 5–295 K with an interval of 10 K. The study of the kinetics of luminescence attenuation made in this study showed that at least three pronounced components are observed in the kinetics of attenuation at low temperature. Of the three components, the main contribution to the light sum is made by a slow microsecond component with a decay time in the range of 2–9 microseconds. However, the nanosecond kinetics of intrinsic luminescence of samples in the ultraviolet region of the spectrum is of particular interest. The presence of several fast components indicates the complex structure of this glow associated with the superposition of the glow bands of autolocalized excitons. The data obtained are of both scientific and practical interest in the further development of functional materials.

About the Authors

А. А. Kissabekova
Margulan University; L.N. Gumilyov Eurasian National University
Kazakhstan

Pavlodat; Astana



N. A. Ispulov
Toraighyrov University
Kazakhstan

Pavlodat



R. N. Аssylbayev
Margulan University
Kazakhstan

Pavlodat



А. B. Bazarbek
L.N. Gumilyov Eurasian National University
Kazakhstan

Astana



А. D. Akylbekova
L.N. Gumilyov Eurasian National University
Kazakhstan

Astana



А. Zh. Zhumabekov
Toraighyrov University
Kazakhstan

Pavlodat



Е. K. Zhetpisbayev
Margulan University
Kazakhstan

Pavlodat



References

1. Kisabekova A., Krasnikov A., Asylbaev R., Baubekova G. Katodolyuminestsentnye kharakteristiki legirovannykh vismutom niobatov lantanoidov // Vestnik Evraziyskogo Natsional'nogo universiteta imeni L.N. Gumileva. Seriya: Fizika. Astronomiya. – 2024. – No. 4 (149) (accepted for publication). In Russ.

2. Baran M., Belikov K., Kissabekova A., Krasnikov A., Lushchik A., Mihokova E., Tsiumra V., Vasylechko L., Zazubovich S., Zhydachevskyy Ya. Origin of luminescence in Bi3+ - doped lanthanide niobates // Journal of Alloys and Compounds. – 2021. – Vol. 859. – Р. 157800. https://doi.org/10.1016/j.jallcom.2020.157800

3. Blasse G., Bril A., J. Investigations on Bi-Activated Phosphors // The Journal of Chemical Physics. – 1968. – Vol. 48. – No. 1. – P. 217–222. https://doi.org/10.1063/1.1667905

4. Sun, H.-T.; Zhou, J.; J. Qui, J. Recent advances in bismuth activated photonic materials // Progress in Material Science – 2014. – Vol. 64. – P. 1–72. https://doi.org/10.1016/j.pmatsci.2014.02.002

5. Bahng H., Oh E. S., Seo S. H., Kim J. S., Lee M., Park H. L., Choong-il Lee, Kim G.C., and Kim K. J. Cathodoluminescence Study of Bi3+ -doped YNbO4 Phosphor. // Phys. stat. sol. – 2002. – Vol.191. – No. 1. – P. 291–295. https://doi.org/10.1002/1521-396X(200205)191:13.0.CO;2-N

6. Sun, H.-T.; Zhou, J.; J. Qui, J. Recent advances in bismuth activated photonic materials // Progress in Material Science. – 2014. – Vol. 64. – P. 1–72. https://doi.org/10.1016/j.pmatsci.2014.02.002

7. Awater R. H. P., Dorenbos P., Towards a General Concentration Quenching Model of Bi3+ Luminescence // J. Lumin. – 2017. – No. 188. – P. 487–489. https://doi.org/10.1016/j.jlumin.2017.05.011

8. Park T.-K., Ahn H.-C., Mho S.-I. High Concentration of Bi3+ Incorporated into RNbO4:Eu3+ (R = La, Y, Gd) as Red Phosphors for White LED Applications // Journal of the Korean Physical Society. – 2008. – Vol. 52. – No. 2. – P. 431–434. https://doi.org/10.3938/jkps.52.431

9. Shin S.H., Jeon D.Y., Suh K.S. Charge-transfer nature in luminescence of YNbO4:Bi blue phosphor // J. Appl. Phys. – 2001. – Vol. 90. – No. 12. – P. 5986–5990. https://doi.org/10.1063/1.1413954

10. Liu Ch., Zhou W., Shi R., Lin L., Zhou R., Chen J., Li Zh., Liang H. Host-sensitized luminescence of Dy3+ in LuNbO4 under ultraviolet light and low-voltage electron beam excitation: energy transfer and white emission / J.Mater. Chem. C. – 2017. – No. 5. – P. 9012. https://doi.org/10.1039/c7tc03260a

11. Han Ch.-H., Kim H.-J., Chang H., Kwon Lee S., Park H.D. Luminescent Properties of YNbO4:Bi Phosphors // Journal of The Electrochemical Society. – 2000. – No. 147(7). – P. 2800–2804. https://iopscience.iop.org/article/10.1149/1.1393609

12. Bang, J.H.; Oh, E.S.; Seo, S.H.; Kim, J.S.; Lee, M.; Park, H.L.; Lee, C.-I.; Kim, C.C.; Kim, K.J. Cathodoluminescence study of Bi3+-doped YNbO4 phosphor // Phys. Status Solidi A. – 2002. – Vol. 191. P. 291–295. https://doi.org/10.1002/1521-396X(200205)191:13.0.CO;2-N

13. Omelkov S. I., Nagirnyi V., Vasil'ev A. N., Kirm M. New features of hot intraband luminescence for fast timing // Journal of Luminescence. – 2016. – No. 176. – P. 309317. https://doi.org/10.1016/j.jlumin.2016.03.039


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For citations:


Kissabekova А.А., Ispulov N.A., Аssylbayev R.N., Bazarbek А.B., Akylbekova А.D., Zhumabekov А.Zh., Zhetpisbayev Е.K. SPECTRAL-KINETIC CHARACTERISTICS OF CATHODOLUMINESCENCE OF LANTHANIDE NIOBATES (Y,Lu,Gd)NbO4:Bi3+. NNC RK Bulletin. 2024;(4):147-152. (In Russ.) https://doi.org/10.52676/1729-7885-2024-4-147-152

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ISSN 1729-7516 (Print)
ISSN 1729-7885 (Online)