Preview

NNC RK Bulletin

Advanced search

STUDY OF TRIBOLOGICAL CHARACTERISTICS OF PROTECTIVE ANTICORROSIVE MoCrN COATINGS

https://doi.org/10.52676/1729-7885-2025-2-64-73

Abstract

Experimental works aimed at studying tribological characteristics of MoCrN coatings have been carried out. Interest in such studies is primarily due to the prospect of using such coatings as anticorrosive protective coatings with high resistance to external mechanical effects, allowing to increase the resistance of steel to degradation processes during operation and high temperatures at which oxidation and amorphization processes are accelerated. The selection of optimal compositions of protective coatings allows to reduce wear resistance and degradation of near-surface layers of steel structures, as well as to increase their resistance to mechanical damage during friction. It is determined that the change of conditions of magnetron sputtering of MoCrN coatings, leading to a change in the ratio of elements in the composition of coatings, leads to the formation of structurally-ordered coatings, which in turn has a good correlation with the results of hardening and increasing resistance to wear. According to the obtained data, the change in the ratio of components, and as a consequence, the change in the ratio of crystalline and amorphous components in the composition of coatings leads to a decrease in the rate of wear, which indicates an increase in the resistance of coatings to external mechanical influences. The test results of coating samples in the case of assessing the resistance of coatings to temperature effects in the process of tribological tests showed an increase in the resistance of coatings due to the variability of changes in the elemental composition and degree of crystallinity.

About the Authors

A. M. Zikirina
Kazakh-British Technical University
Kazakhstan

Almaty



E. A. Kenzhin
Kazakh-British Technical University
Kazakhstan

Almaty



D. I. Shlimas
Kazakh-British Technical University; L.N. Gumilev Eurasian National University
Kazakhstan

Almaty

Astana



A. L. Kozlovskiy
L.N. Gumilev Eurasian National University
Kazakhstan

Astana



References

1. Fenker M. et al. Formation of solid lubricants during high temperature tribology of silver-doped molybdenum nitride coatings deposited by dcMS and HIPIMS // Coatings. – 2021. – Vol. 11, No. 11. – P. 1415.

2. Liu C. et al. Influence of copper on the compositions, mic rostructure and room and elevated temperature tribological properties of the molybdenum nitride film // Surface and Coatings Technology. – 2020. – Vol. 395. – P. 125811.

3. Gilewicz A., Warcholinski B., Murzynski D. The proper ties of molybdenum nitride coatings obtained by cathodic arc evaporation // Surface and Coatings Technology. – 2013. – Vol. 236. – P. 149-158.

4. Hudec T. et al. Tribological behaviour of Mo-SN solid lubricant coatings in vacuum, nitrogen gas and elevated temperatures // Surface and Coatings Technology. – 2021. – Vol. 405. – P. 126722.

5. Liu C. et al. Tribological properties of Mo2N films at ele vated temperature // Coatings. – 2019. – Vol. 9, No. 11. – P. 734.

6. Wang J. et al. Nanostructured molybdenum nitride-based coatings: Effect of nitrogen concentration on microstructu re and mechanical properties // Thin Solid Films. – 2019. – Vol. 682. – P. 82–92.

7. Polcar T., Parreira N. M. G., Cavaleiro A. Tribological characterization of tungsten nitride coatings deposited by reactive magnetron sputtering // Wear. – 2007. – Vol. 262, No. 5–6. – P. 655–665.

8. Rakhadilov B.K. et al. Inves tigation of tribological properties of detonation coatings based on aluminum oxide and tungsten carbide // NNC RK Bulletin. – 2023. No. 3. – P. 168–173. (In Russ.) https://doi.org/10.52676/1729-7885-2023-3-168-173

9. Liu Y., Shi J. Design of a smart protective coating with molybdate-loaded halloysite nanotubes towards corrosion protection in reinforced concrete // Cement and Concrete Composites. – 2024. – Vol. 147. – P. 105419.

10. Shuai W. et al. Preparation and characterization of La doped Y3Al5O12 as a potential protective coating materi al against CMAS corrosion // Surface and Coatings Tech nology. – 2024. – Vol. 476. – P. 130188.

11. Thakran M., Lata S. Polybenzopyrrole/nano-alumina composite blend with zirconium silicate reinforced epoxy as protective coating to subside corrosion of carbon steel within a dilute NaCl solution // Journal of Molecular Structure. – 2024. – Vol. 1298. – P. 137068.

12. Belgroune A. et al. In Vitro Corrosion and Wear Investi gation of Multifunctional TiAlMoN Sputtered Coatings on Cold-Sprayed SS316L // ACS Applied Engineering Materials. – 2024. – Vol. 2, No. 2. – P. 345–359.

13. Yang Q. Wear resistance and solid lubricity of molybdenum-containing nitride coatings deposited by cathodic arc evaporation // Surface and Coatings Technology. – 2017. – Vol. 332. – P. 283–295.

14. Yi B. et al. The influences of pulsed bias duty cycle on tribological properties of solid lubricating TiMoCN coatings // Vacuum. – 2020. – Vol. 180. – P. 109552.

15. Ibrahim K. et al. A first-principles study of the electronic, structural, and optical properties of CrN and Mo: CrN clusters // Ceramics International. – 2019. – Vol. 45, No. 14. – P. 17094–17102.

16. Kenzhin Ye.A. et al. Investigation of varia tion of spraying conditions on variation of strength characteristics of MoCrN coatings // NNC RK Bulletin. 2024. No. 2. – P. 120–127. (In Russ.) https://doi.org/10.52676/1729-7885-2024-2-120-127


Review

For citations:


Zikirina A.M., Kenzhin E.A., Shlimas D.I., Kozlovskiy A.L. STUDY OF TRIBOLOGICAL CHARACTERISTICS OF PROTECTIVE ANTICORROSIVE MoCrN COATINGS. NNC RK Bulletin. 2025;(2):64-73. (In Russ.) https://doi.org/10.52676/1729-7885-2025-2-64-73

Views: 4


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 1729-7516 (Print)
ISSN 1729-7885 (Online)