ACID MODIFICATION OF BENTONITES KALZHAT AND ORTA TENTEK AND STUDY THEIR PHYSICOCHEMICAL PROPERTIES
https://doi.org/10.52676/1729-7885-2025-3-77-85
Abstract
In this work was investigated the methods of acid modification of bentonite clays from the Kalzhat and Orta Tentek deposits located in the Almaty region of Republic Kazakhstan with sulfuric and nitric acid in various concentrations and determined the effective concentration. In this study, the effective concentrations of 20% H2SO4 and 10% HNO3 were selected, because bentonite was modified with 10–98% H2SO4 and 10–65% HNO3 acids during the study. Among these concentrations, according to the results of various studies, 20% H2SO4 and 10% HNO3 acids were found to be effective, and the concentrations given in this work were considered effective. The obtained results were studied by the IR-spectroscopy FTIR, X-ray fluorescence, X-ray diffractometer and scanning electron microscope methods. Bentonite modification has a positive effect on opening the interlayer space of clay and improving its properties. After purification and modification, bentonite clay can be used in agriculture, manufacturing, medicine, and various fields such as drilling, construction and water purification.
About the Authors
K. ArypKazakhstan
Almaty
S. Kabdrakhmanova
Kazakhstan
Almaty
S. Nauryzova
Kazakhstan
Almaty
E. Shaimardan
Kazakhstan
Almaty
N. Kantay
Kazakhstan
Almaty; Ust-Kamenogorsk
A. Zh. Kerimkulova
Kazakhstan
Almaty
M. M. Beisebekov
Kazakhstan
Almaty
A. D. Kukhareva
Kazakhstan
Almaty
N. Berdibay
Kazakhstan
Almaty
References
1. Mohamed Chokri, Omar Azougagh, Imad El Bojaddayni, Ilyas Jalafi, Youssef El Ouardi, Issam Jilal, Mhamed Ahari, Amin Salhi, Abderrahmane El Idrissi, Amine Bendahhou, Mohamed Abou-Salama, Soufian El Barkany, Progress in bentonite clay modification and enhancing properties to industrial applications: A review // Materials Chemistry and Physics. - 2025. - Vol. 337. https://doi.org/10.10167j.matchemphys.2025.130486
2. Beysebekov МД. Dэrilik preparattardy immobilizatsiyalau, Almaty 2006 (In Kaz.)
3. Selma Osmica, Amra Odobasicb, Sabina Begic, The Influence of Acid Activation on Surface Characteristics of Natural Bentonite // Int. Res. J. of Pure and Appl. Chem. -2024. -Vol. 25. - P. 35-42, https://doi.org/10.9734/irjpac/2024/v25i5873
4. Huan Xi, Qingqing Li, Yan Yang, Jianfeng Zhang, Feng Guo, Xiaogang Wang, Shikai Xu and Shiping Ruan, Synergistic modification of bentonite by acid activation and hydroxyl iron pillaring for enhanced dye adsorption capacity // Water Sci. Technol. - 2020. - Vol 81 (7). -P.1518-1529. https://doi.org/10.2166/wst.2020.239
5. Zhuang, Guanzheng; Zhang, Zepeng; Fu, Meng; Ye, Xian; Liao, Libing. Comparative study on the use of cationic-nonionic-organo-montmorillonite in oilbased drilling fluids // Applied Clay Science. - 2015. - Vol. 116-117. -Р. 257-262. http://doi:10.1016/j.clay.2015.04.004
6. Carrado, K.A. and Komadel, P. Bentonites-Versatile Clays: Acid Activation of Bentonites and Polymer-Clay Nanocomposites // Elements. - 2009. - Vol. 5. - P. 111-116.
7. Hajira T., Muhammad S., Zainab Q. Physiochemical Modification and Characterization of Bentonite Clay and Its Application for the Removal of Reactive Dyes // International Journal of Chemistry. - 2013. https://doi.org/10.5539/ijc.v5n3p19
8. David A. DAmico, Romina P. Ollier, Vera A. Alvarez, Walter F. Schroeder, Viviana P. Cyras. Modification of bentonite by combination of reactions of acid-activation, silylation and ionic exchange // Applied Clay Science. – 2014. – Vol. 99.
9. Surendra B.S., Veerabhadraswamy M. Microwave Assisted Modification of Bentonite Clay: Characterization and Solvent Free Synthesis of Schiff’s Bases // Journal of Organic & Inorganic Chemistry. – 2017. – Vol. 3. https://doi.org/10.21767/2472-1123.100023
10. Samira Bendou, Moussa Amrani, Effect of Hydrochloric Acid on the Structural of Sodic-Bentonite Clay // Journal of Minerals and Materials Characterization and Engineering. – 2014. – Vol. 2. – P. 404–413. https://doi.org/10.4236/jmmce.2014.25045
11. G.V. Pankina, P.A. Chernavskii, Ye.S. Lokteva, V.V. Lunin Optimization of acidic treatment of bentonitic clays from the national layers // Vestnik MGU. Seriya “Khimiya”. - 2010. - Vol. 51. - No. 2. - P. 75-80. (In Russ.) URL: https://www.chem.msu.ru/rus/vmgu/102/75.pdf
12. Akimbaeva A.M., Ergozhin E.E. Otsenka strukturnykh i sorbtsionnykh kharakteristik aktivirovannogo betonita // Kolloid. zhurn. - 2007. - Vol. 69, - No. 4. - P. 437-443. (In Russ.)
13. Vijendra Kumar Gupta, Manisha Sharma, Raj K. Vyas. Hydrothermal modification and characterization of bentonite for reactive adsorption of methylene blue: An ESI-MS study // Journal of Environmental Chemical Engineering. – 2015. – Vol. 3. – P. 2172–2179. https://doi.org/10.1016/j.jece.2015.07.022
14. Madejová J., Kečkéš J., Pálková H., Komadel P. // J. Clay Minerals. – 2002. – Vol. 37 (2). – P. 377.
15. Bishop J, Pieters C, Edwards J. // J. Clays and Clay Minerals. – 1994. – Vol. 42. – P. 702.
16. Steudel, A., Batenburgm, L.F., Fisher, H.R., Weidler, P.G. and Emmerich, K. Alteration of Swelling Clays by Acid Treatment // Applied Clay Science. – 2009. – Vol. 44. – P. 105–115. https://doi.org/10.1016/j.clay.2009.02.002
17. Vu Cong Khang et al 2016 IOP Conf. Ser.: Earth Environ. Sci. 43 012004
18. Madejová J., Komadel P. // J. Clays and Clay Minerals. – 2001. – Vol. 49 (5). – P. 410.
19. Widjaya R., Juwono A., Rinaldi N. Bentonite modification with pillarization method using metal stannum // AIP Conference Proceedings. – 2017. – Vol. 1904. – Article 020010. https://doi.org/10.1063/1.5011867.
20. Satria Jaya Priatna, Yusuf Mathiinul Hakim, Sahrul Wibyan, Siti Sailah, Risfidian Mohadi. Interlayer Modification of West Java Natural Bentonite as Hazardous Dye Rhodamine B Adsorption // Science and Technology Indonesia. – 2023. – Vol. 8. – P. 160–169. https://doi.org/10.26554/sti.2023.8.2.160-169
Supplementary files
Review
For citations:
Aryp K., Kabdrakhmanova S., Nauryzova S., Shaimardan E., Kantay N., Kerimkulova A.Zh., Beisebekov M.M., Kukhareva A.D., Berdibay N. ACID MODIFICATION OF BENTONITES KALZHAT AND ORTA TENTEK AND STUDY THEIR PHYSICOCHEMICAL PROPERTIES. NNC RK Bulletin. 2025;(3):77-85. https://doi.org/10.52676/1729-7885-2025-3-77-85










