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INVESTIGATION OF TUNGSTEN SURFACE CARBIDIZATION UNDER PLASMA IRRADIATION

https://doi.org/10.52676/1729-7885-2021-3-37-43

Abstract

This paper presents the results of a study of the formation of a carbidized layer under various experimental conditions and the choice of optimal parameters for carbidization of a tungsten surface under plasma irradiation. To study the effect of the surface temperature of a tungsten sample and the duration of plasma irradiation, experiments were carried out at a sample surface temperature of 1300 °C and 1700 °C with an irradiation duration of 300–2400 s. Analysis of the research results showed that the maximum formation of W2C on the surface is observed at a test temperature of 1700 °C. At a temperature of 1300 °C, the phase composition of the carbidized layer depends on the duration of plasma irradiation. According to the literature analysis, the formation of WC occurs on the surface of tungsten, from which C diffuses into the particle and forms the underlying layer of W2C. With an increase in the ion fluence, depending on the irradiation time and the temperature of the sample surface, the diffusion of C into W accelerates, the WC content decreases, and W2C becomes the dominant carbide compound.

About the Authors

G. K. Zhanbolatova
Branch “Institute of Atomic Energy” RSE NNC RK
Kazakhstan

Kurchatov



A. Z. Miniyazov
Branch “Institute of Atomic Energy” RSE NNC RK
Kazakhstan

Kurchatov



T. R. Tulenbergenov
Branch “Institute of Atomic Energy” RSE NNC RK
Kazakhstan

Kurchatov



I. A. Sokolov
Branch “Institute of Atomic Energy” RSE NNC RK
Kazakhstan

Kurchatov



O. S. Bukina
Branch “Institute of Atomic Energy” RSE NNC RK
Kazakhstan

Kurchatov



References

1. M. Merola, F. Escourbiac, R. Raffray, P. Chappuis, T. Hirai, A. Martin. Overview and status of ITER internal components // Fusion Eng. Des. – 2014. – V. 89. – P. 890–895.

2. S.E. Lee, Y. Hatano, M. Tokitani et al. Global distribution of tritium in JET with the ITER-like wall // Nuclear Materials and Energy. – 2021. – Vol. 26. – P. 100930

3. Tazhibayeva I.L. [et al.] KTM Experimental Complex Project Status // Fusion Science and Technology. – Vol. 47. – 2005. – P. 746–750.

4. Michael B.Z., Jingguang G.C. Synthesis, characterization and surface reactivity of tungsten carbide (WC) PVD films // Surface Science. – Vol. 569. – P. 89–98.

5. Romanusa H., Cimallaa V., Schaefera J.A., Spieûb L., Eckec G., Pezoldtc J. Preparation of single phase tungsten carbide by annealing of sputtered tungsten-carbon layers // Thin Solid Films. – 2000. – Vol. 359. – P. 146–149.

6. J. Luthin, Ch. Linsmeier. Carbon films and carbide formation on tungsten // Surface Science. – 2000.– Vol. 454–456. – P. 78–82.

7. Ch. Linsmeier, J. Luthin, K. U. Klages, A. Wiltner and P. Goldstraß. Formation and Erosion of Carbon-Containing Mixed Materials on Metals // Physica Scripta. – 2004. – Vol. T111. – P. 86–91.

8. Ch. Linsmeier, M. Reinelt, K. Schmid. Surface chemistry of first wall materials – From fundamental data to modeling // Journal of Nuclear Materials. – 2011. – Vol. 415. – P. S212–S218.

9. P. Wang, W. Jacob. Deuterium diffusion and retention in a tungsten–carbon multilayer system // Nuclear Instruments and Methods in Physics Research B. – 2014. – Vol. 329.– P. 6–13

10. Pavlov B.A., Terent'ev A.P. Kurs organicheskoy khimii. – Izdanie shestoe, stereotipnoe. – Moscow.: Izd-vo Khimiya, 1967. – P. 58.

11. Sokolov I.A., Skakov M.K., Miniyazov A.Zh., Tulenbergenov T.R. Izuchenie protsessov obrazovaniya karbidov na poverkhnosti divertora termoyadernogo reaktora. – Vestnik KazNAEN. – 2019. – Issue 1.– P. 44–49.

12. Zhanbolatova Ғ.Қ., Baklanov V.V., Tulenbergenov T.R., Miniyazov A.Zh., Sokolov I.A. Karbidizatsiya poverkhnosti vol'frama v puchkovo-plazmennom razryade. – Vestnik NYaTs RK. – 2020. – Issue 4. – P. 77–81.

13. Patent RK № 2080. Imitatsionnyy stend s plazmennopuchkovoy ustanovkoy / Kolodeshnikov A.A., Zuev V.A., Ganovichev D.A., Tulenbergenov T.R. [i dr.]; zayavitel' i patentoobladatel' RGP NYaTs RK. – No. 2016/0108.2; zayavl. 29.02.2016; opubl. 15.03.2017, Byul. No. 5. – 3 p.

14. Kurnaev V., Vizgalov I., Gutorov K., Tulenbergenov T., Sokolov I., Kolodeshnikov A., Ignashev V., Zuev V., Bogomolova I., Klimov N. Investigation of plasmasurface interaction at plasma beam facilities // Journal of Nuclear Materials. – 2015. – Vol. 463.–P. 228–232. – http://dx.doi.org/10.1016/j.jnucmat.2014.12.076.

15. Gražulis S., Chateigner D., Downs R.T., Yokochi A.F.T., Quirós M., Lutterotti L., Manakova E., Butkus J., Moeck P. and Le Bail A. Crystallography Open Database – an open-access collection of crystal structures // J. Appl. Cryst. – 2009. – Vol. 42. – P. 726–729.


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For citations:


Zhanbolatova G.K., Miniyazov A.Z., Tulenbergenov T.R., Sokolov I.A., Bukina O.S. INVESTIGATION OF TUNGSTEN SURFACE CARBIDIZATION UNDER PLASMA IRRADIATION. NNC RK Bulletin. 2021;(3):37-43. (In Russ.) https://doi.org/10.52676/1729-7885-2021-3-37-43

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ISSN 1729-7885 (Online)